(b) Identify the phosphorus-containing compounds C to F in the following reaction scheme and draw their structures, showing the stereochemistry at the main group element centres: 2 EtMgBr LiAlH4 PC|3 C D BuLi Me3SiCI F E
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- CN -CN H30® /A (A); Product (A) of the reaction is : CN CN (a) (b) CO2H (c) (d) CO2H(a) Draw the structures ofA to E in the following reactions. он 1. LIAIH, 2. H0 PCC 00 Lindiar's catalyst OH (CH,COOH THOCHICH,lla (*DET 1. RCOH 2. HO10. The following reaction has variation of free energy value of AG = -2.1 kJ/mol CH;Br + H2S 2 CH;SH + HBr (a) Calculate Keq at room temperature (25°C) for this reaction as written. (b) Starting with a 1 M solution of CH3B and H2S, calculate the final concentrations of all four species at equilibrium.
- C Metallic Tanta C The Substance C The Substance C The Substance C Which Of The C Get Homewor O 8 https://east.cengagenow.com film/takeAssignment/takeCovalentActivity.do?locator=assignment-take O Other Bookmarks [References) Use the References to access important values if needed for this question. In a study of the rearrangement of cyclopropane to propene at 500 °C (CH2)3 CH3CH=CH2 the concentration of (CH2)3 was followed as a function of time. It was found that a graph of In[(CH2)3] versus time in seconds gave a straight line with a slope of -1.02x10-3 s-1 and a y-intercept of -2.77. Based on this plot, the reaction is Norder in (CH2)3 and the rate constant for the reaction is s-1 zero first Submit Answer Try Another V second item attempts remaining Previnus Next 7:13 PM 5/5/2022 SONY WEB DISPLAY OFF One Touch Web Access Without Booting Up F8 Num Lk Ser Lk Prt Sc Sys Rq Insert Pause Delete Break F4 F5 F6 F7 F9 F10 F11 F12 -Backspace HomeQ.4 Identify the structures of A and B from the following reaction. Provide a suitable justification or the formation of these products/- NNHTS NNHTS NABD, NaBH, A B CH;CO,H CH,CO,D indOne of the steps in fat metabolism is the hydration of crotonate to yield 3-hydroxybutyrate. This reaction occurs by addition of —OH to the Si face at C3, followed by protonation at C2, also from the Si face. Draw the product of the reaction, showing the stereochemistry of each step.
- Azo dyes are the major source of artificial color in textiles and food. Part of the reason for their intense coloring is the conjugation from an electron-donating group through the diazo bridge (—N=N—) to an electron-with drawing group on the other side. For the azo dyes below, draw a resonance form that shows how the electron-donating group is related to the electron-with drawing group on the other side of the diazo bridge. Used curved arrows to show how the electrons are reorganized.(a) What is the hybridization of the nitrogen in each of the following compounds? (b) How does hybridization affect the availability of the lone pair and the basicity of each compound?Provide the products or reagents necessary for the following reactions. Include stereochemistry when applicable. A) B) Co,H CO,H CO,H
- Explain the following: (a) The peroxide ion, O22 - , has a longerbond length than the superoxide ion, O2-. (b) The magneticproperties of B2 are consistent with the p2p MOs being lowerin energy than the s2p MO. (c) The O22 + ion has a strongerO—O bond than O2 itself.(b) Reactivity with the S1 by the treatment with NaOH Br Br I t 2 (c) Solubility in hexane: Br H3C-BrConsider a hypothetical chemical reaction between compound A and compound B, which produces compound C as the final product. The reaction is known to be exothermic and spontaneous. However, when the reaction is carried out under certain conditions, it fails to occur. Explain this observation and propose a potential solution to overcome this hurdle.