Calculate the vibrational partition function of CI4 at 500 K given the wavenumbers 178 cm−1 (symmetric stretch, non-degenerate), 90 cm−1 (deformation, doubly degenerate), 555 cm−1 (deformation, triply degenerate), 125 cm−1 (deformation, triply degenerate).

Calculate the vibrational partition function of CI4 at 500 K given the wavenumbers 178 cm−1 (symmetric stretch, non-degenerate), 90 cm−1 (deformation, doubly degenerate), 555 cm−1 (deformation, triply degenerate), 125 cm−1 (deformation, triply degenerate).

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter18: More Statistical Thermodynamics

Section: Chapter Questions

Problem 18.32E

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Question

Calculate the vibrational partition function of CI₄ at 500 K given the wavenumbers 178 cm⁻¹ (symmetric stretch, non-degenerate), 90 cm⁻¹ (deformation, doubly degenerate), 555 cm⁻¹ (deformation, triply degenerate), 125 cm⁻¹ (deformation, triply degenerate).

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