Describe the differences between: a) Monomer and repeating unit b) Polycondensation and polyaddition c) Polymer configuration and polymer conformation besa molar mass of 3
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- Page 12 of 13 4. Give TWO (2) examples of polymers that can used as a resin in mounting process. 1. 2. 5.Fill in the blank with the following: [grain boundary, dislocation, coarse, stronger] A fine-grained material (one that has small grains) is harder and that is area to impede than one -grained, because the former has a greater total movement. 6. Label ferrite and pearlite in the following photomicrographs of a PCS specimen. 7. Which one is coarser? ANS: (a) Abrasive paper: 180 grit paper or 320 grit paper ANS: (b) Metal specimen: ASTM grain-size number; 4 or 10Polymer Engineering question: Explain doping process and why this process important for conductive polymer?Q5 (a) Figure 6 shows two types of polymeric products fabricated using different processing techniques. Suggest with justification for the type of processes used to produce the products: i. Product A ii. Product B A B Figure 6. Two types of polymeric products (a) plastic bottles and (b) plastic car boot tray (b) The molecular weight data of a Polymer X are given in Table 3. Once undergone a melting process, it achieves degree of polymerization, DP of 498 upon solidification. i. Calculate the number-average molecular weight (Mn) for the polymer. ii. Calculate the molecular weight for monomers of the Polymer X. iii. Prove that the Polymer X is a polytetrafluoroethylene (PTFE) with chemical formula of (C2F4)n- Given the atomic weights for carbon, C is 12.011 g/mol and fluorine, F is 18.998 g/mol.
- There are 4 classifications of structural molecular characteristics of polymers - Linear, Network, Crosslinked. What is the final type? Answer:Draw stress-strain graphs for two polymers: one is stiffer than the other and exhibits ayield point and the other shows no clear yield point but is much tougher.An unknown polymer sample was found to have the following molecular weight distribution: Molecular weight range 8,000 - 20,000 20,000 - 32,000 32,000 - 44,000 44,000 - 56,000 56,000 - 68,000 68,000 -80,000 80,000 - 92,000 0.03 Knowing that the monomer is methyl methacrylate, which of the below is the number average degree of polymerization for this polymer sample? Select one: O a. O b. DP 476 O C. DP = 338 DP = 664 O d. DP 544 O e. DP = 801 Xi 0.05 0.15 0.21 0.28 0.18 0.10 Wi 0.02 0.08 0.17 0.29 0.23 0.16 0.05
- An unknown polymer sample was found to have the following molecular weight distribution: Molecular weight range xi 8,000 -20,000 0.05 20,000 - 32,000 0.15 32,000 44,000 0.21 44,000 56,000 0.28 56,000 -68,000 0.18 68,000 - 80,000 0.10 80,000 - 92,000 0.03 Having a DP=763, which of the following common polymers is this sample? Select one: wi 0.02 0.08 0.17 0.29 0.23 0.16 0.05 a. Polymethylmethacrylate with a monomer molecular weight of 100.121 g/mol b. Polyvinyl chloride with a monomer molecular weight of 62.498 g/mol c. Polycarbonate with a monomer molecular weight of 61.0168 g/mol d. Polypropylene with a monomer molecular weight of 42.08 g/mol e. Polystyrene with a monomer molecular weight of 104.15 g/mola) List down the four molecular structures for polymers. Discuss in detail how the four molecular structures affect the level of strength of the resulting polymers according to their order. b) Define composites. Describe the phase present in composites. With time,the use of composite in aircraft body has increased to 50% discuss the advantages of composites as compared to conventional materials in aerospace industry c) List down one processing method for production of composite tubes made of fiber reinforced polymer.Briefly describe the processing steps involved.Please make sure to display your thought process? It is imperative to be able to follow how the answer was deduced. Please be as thorough as possible. Please address all parts of this question as they are all part and critical to answering this question correctly. Please show good integrity when answering the question: Strain-rate, temperature, pressure, and aging time all affect the stress/strain behavior of polymers. Draw a stress-strain curve below for a typical ductile polymer. Clearly label the yield point and the ultimate tensile strength. Using this curve draw two new curves corresponding to same polymer but now tested at: 1) an increase in temperature and 2) an increase in strain rate. Explain what happens to the tensile behavior after: a) a prolong time of aging time is increased and b) when the tensile tests are conducted under super imposed hydrostatic compression
- A polymer has creep behaviour that can be represented as a power law equation: e = 0 (Jo + Jit") where J, is 0.5 GPa1, J1 is 0.45 GPa's 0.3 and n is 0.3 (with t in seconds). A component of this material has the following applied stress history: There is no stress before t = 0 A positive (tensile) stress of 8 MPa is applied from t = 0 for 4 hours From t = 4 hours to 6 hours, the stress is compressive stress of 2 MPa The stress is then removed. What will the strain in the material be at t = 9 hours? Enter your value as a number to 4 decimal places. You have a 2% error margin with this.A cylindrical acetal polymer bar 64 cm long and 1.27 cm in diameter is subjected to a vibrational (tension) load at a frequency of 501 vibrations per minute with a load of 4,849 N. How many hours will the part survive before breaking? Use stress = force/area and WATCH YOUR UNITS!!When answering the following questions , ensure that you explain in terms of both the microscopic and macroscopic structure of the materials. A) polymer - explain the difference in structure between a thermoplastic and thermoset material and explain how the structure accounts for the key generic properties of those polymers. B) composite material - for a particular composite and a fibre reinforce composite , explain the difference in structure and whst structual features dictate the properties of the material.