(do last four asap ) On the basis of the 18-electron rule, identify the first-rowtransition metal for each of the following:а. [MСОb. H;CM(CO);c. M(CO),(CS)(PPh;)Brd. [(7-C,H;(7-C,H;)M(CO)]OCH3e.(OC),M=CCH5f. [(n-C,H)(7-C;Hs)M]*g. (7-C,H;X7-C;H;)M(CH;)(NO) (has linearly coor-dinated NO)h. [M(CO),I(diphos)](diphos1,2-bis(diphenylphosphino)ethane)

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Answered: On the basis of the 18-electron rule,…

On the basis of the 18-electron rule, identify the first-row transition metal for each of the following: a. [M(CO);]+ b. H;CM(CO); c. M(CO),(CS)(PPh;)Br

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter26: Molecular Absorption Spectrometry

Section: Chapter Questions

Problem 26.15QAP

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Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

(do last four asap )

On the basis of the 18-electron rule, identify the first-row
transition metal for each of the following:
а. [MСО
b. H;CM(CO);
c. M(CO),(CS)(PPh;)Br
d. [(7-C,H;(7-C,H;)M(CO)]
OCH3
e.
(OC),M=C
CH5
f. [(n-C,H)(7-C;Hs)M]*
g. (7-C,H;X7-C;H;)M(CH;)(NO) (has linearly coor-
dinated NO)
h. [M(CO),I(diphos)]
(diphos
1,2-bis(diphenylphosphino)ethane)

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