roposed mechanism: 3 K₁ K-₁ +03 0₂ + O K₂ Questions: 20₂ 2 03 3 0₂ (fast equilibrium) (much slower irrev. step) (net rxn, gas phase) Experimental Observations: • Double initial [03] ==> rate inc • Add [O₂] initially ==> rate drop (1) What is the chemical flux eqn for the proposed mechanism in terms of +d[0₂] (2) What is the SSA eqn for [O]? (3) What is the derived rate law for this mechanism in terms of +d[0₂]/dt? (4) Based on the exptl observations and derived overall rate law, is the proposed mechanism a plausible one for this rxn?

roposed mechanism: 3 K₁ K-₁ +03 0₂ + O K₂ Questions: 20₂ 2 03 3 0₂ (fast equilibrium) (much slower irrev. step) (net rxn, gas phase) Experimental Observations: • Double initial [03] ==> rate inc • Add [O₂] initially ==> rate drop (1) What is the chemical flux eqn for the proposed mechanism in terms of +d[0₂] (2) What is the SSA eqn for [O]? (3) What is the derived rate law for this mechanism in terms of +d[0₂]/dt? (4) Based on the exptl observations and derived overall rate law, is the proposed mechanism a plausible one for this rxn?

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 11.33PAE: The following experimental data were obtained for the reaction of \'I14* and NOf in acidic solution....

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