se/3594/report/69138 #tab=REPORTRTeport Submission - ThermochemistryPart B data and calculationsAssigned saltMass of dry, empty calorimeter (g)Final mass of calorimeter and mixture (g)Mass of solution (g)Initial temperature (°C)Final temperature (°C)Change in temperature of solution (°C)arxn(J)(report the appropriate sign)Mass of salt (g)Moles of salt (mol)Enthalpy of Dissolution (J/mol)Enthalpy of Dissolution (kJ/mol)Dubon Reina, Sam (CDT)dubonres@myumanitoba.caTable viewList viewMeasurement or CalculationNaCl25.32127.12101.822.121.6-0.5212.833.000.051

Part 2: Explanation:Step 1: Convert heat change from J to kJ.Given that 1 kJ = 1000 J, we divide the…

Answered: se/3594/report/69138 #tab=REPORT RT…

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter6: Thermochemistry

Section: Chapter Questions

Problem 104AE

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Determine whether the statements given below are true or false. Consider enthalpy (H). (a) It is a state property. (b) qreaction(atconstantP)=H=HproductsHreactants (c) The magnitude of H is independent of the amount of reactant. (d) In an exothermic process, the enthalpy of the system remains unchanged.
A 29.1-mL sample of 1.05 M KOH is mixed with 20.9 mL of 1.07 M HBr in a coffee-cup calorimeter (see Section 6.6 of your text for a description of a coffee-cup calorimeter). The enthalpy of the reaction, written with the lowest whole-number coefficients, is 55.8 kJ. Both solutions are at 21.8C prior to mixing and reacting. What is the final temperature of the reaction mixture? When solving this problem, assume that no heat is lost from the calorimeter to the surroundings, the density of all solutions is 1.00 g/mL, and volumes are additive.
In a constant-volume calorimeter, 35.0g of H2cools from 75.3C to25.0C. Calculate w, q, U, and H for the process.
Starting with equation 2.27 andthe original definitionof enthalpy, derive the fact that Cp-=Cv-+R
How much heat is produced when loo mL of 0.250 M HCl (density, 1.00 g/mL) and 200 mL of 0.150 M NaOH (density, 1.00 g/mL) are mixed? HCl(aq)+NaO(aq)NaCl(aq)+H2O(l)H298=58kJ If both solutions are at the same temperature and the heat capacity of the products is 4.19 J/g C, how much will the temperature increase? What assumption did you make in your calculation?
• define work and beat using the standard sign conventions.
In the 1880s, Frederick Trouton noted that the enthalpy of vaporization of 1 mol pure liquid is approximately 88 times the boiling point, Tb, of the liquid on the Kelvin scale. This relationship is called Troutons rule and is represented by the thermochemical equation liquid gas H = 88 Tb, joules Combined with an empirical formula from chemical analysis, Troutons rule can be used to find the molecular formula of a compound, as illustrated here. A compound that contains only carbon and hydrogen is 85.6% C and 14.4% H. Its enthalpy of vaporization is 389 J/g, and it boils at a temperature of 322 K. (a) What is the empirical formula of this compound? (b) Use Troutons rule to calculate the approximate enthalpy or vaporization or one mole of the compound. Combine the enthalpy of vaporization per mole with that same quantity per gram to obtain an approximate molar mass of the compound. (c) Use the results of parts (a) and (b) to find the molecular formula of this compound. Remember that the molecular mass must be exactly a whole-number multiple of the empirical formula mass, so considerable rounding may be needed.
Consider the combustion of propane: C3H8(g)+5O2(g)3CO2(g)+4H2O(l)H=2221KJ Assume that all the heat in Example 7-3 comes from the combustion of propane. What mass of propane must be burned to furnish this amount of energy assuming the heat transfer process is 60.% efficient?
When a 0.740-g sample of trinitrotoluene (TNT), C7H5N2O6, is burned in a bomb calorimeter, the temperature increases from 23.4 C to 26.9 C. The heat capacity of the calorimeter is 534 J/C, and it contains 675 mL of water. How much heat was produced by the combustion of the TNT sample?
Would the amount of heat absorbed by the dissolution in Example 5.6 appear greater, lesser, or remain the same if the heat capacity of the calorimeter were taken into account? Explain your answer.

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