. d. A change of state from state 1 to state 2 produces a greater increase in entropy when carried out irreversibly than when done reversibly. e. The heat q for an irreversible change of state from state 1 to 2 might differ from the heat for the same change of state carried out reversibly. f. For a reversible isothermal process in a closed system, ΔS must be zero. g.The system's entropy change for an adiabatic process in a closed system must be zero. h.Thermodynamics cannot calculate ΔS for an irreversible process.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter13: Spontaneous Processes And Thermodynamic Equilibrium
Section: Chapter Questions
Problem 20P
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True or False. Explain your answers. a. For every cyclic process, the final state of the system is the same as the initial state. b. For every cyclic process, the final state of the surroundings is the same as the initial state of the surroundings. c. U and H depend only on T for a perfect gas. d. A change of state from state 1 to state 2 produces a greater increase in entropy when carried out irreversibly than when done reversibly. e. The heat q for an irreversible change of state from state 1 to 2 might differ from the heat for the same change of state carried out reversibly. f. For a reversible isothermal process in a closed system, ΔS must be zero. g.The system's entropy change for an adiabatic process in a closed system must be zero. h.Thermodynamics cannot calculate ΔS for an irreversible process.

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