( do no 1 with explanation any 4 rxn) 1. Identify the following reactions by type and predict the products (any 4):(i)(ii)(iii)(iv)(v)2. "Selectivity of Wilkinson's catalyst is largely a consequence of the bulky triphenylphosphine ligands, thePt(O2) (PPH3)2 + 2CS2RhH(CO)(PPH3)3 +CF.[C,H,Mn (CO);]* + HCH;Mn(CO), + C,H&NH2IrCI(PMe,); + HCOselectivity can be fine-tunned by using phosphines having different cone angles than PPh;" Explain

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1. Identify the following reactions by type and predict the products (any 4): (i) (ii) (iii) (iv) (v) Pt(O,) (PPh;)2 + 2CS2 RhH(CO)(PPh;)3 +CF. [C,H,Mn (CO)3]* +H CH;Mn(CO), + C,H;NH, IrCI(PMe;), + HCO

1. Identify the following reactions by type and predict the products (any 4): (i) (ii) (iii) (iv) (v) Pt(O,) (PPh;)2 + 2CS2 RhH(CO)(PPh;)3 +CF. [C,H,Mn (CO)3]* +H CH;Mn(CO), + C,H;NH, IrCI(PMe;), + HCO

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds

Section: Chapter Questions

Problem 117QRT

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Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

( do no 1 with explanation any 4 rxn)

1. Identify the following reactions by type and predict the products (any 4):
(i)
(ii)
(iii)
(iv)
(v)
2. "Selectivity of Wilkinson's catalyst is largely a consequence of the bulky triphenylphosphine ligands, the
Pt(O2) (PPH3)2 + 2CS2
RhH(CO)(PPH3)3 +CF.
[C,H,Mn (CO);]* + H
CH;Mn(CO), + C,H&NH2
IrCI(PMe,); + HCO
selectivity can be fine-tunned by using phosphines having different cone angles than PPh;" Explain

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