Homework Help is Here – Start Your Trial Now!
Science
Chemistry
10.5. The rate of formation of the product of a reaction is found to give a nonlinear Arrhenius plot, the line being convex to the 1/T axis (i.e., the activation energy is higher at higher temperatures). Suggest a reason for this type of behavior. (Hint: For this and the following problem, consider the possibility of two parallel reactions and of two consecutive reactions having different activation energies.)

10.5. The rate of formation of the product of a reaction is found to give a nonlinear Arrhenius plot, the line being convex to the 1/T axis (i.e., the activation energy is higher at higher temperatures). Suggest a reason for this type of behavior. (Hint: For this and the following problem, consider the possibility of two parallel reactions and of two consecutive reactions having different activation energies.)

Chemistry: Principles and Practice
Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter13: Chemical Kinetics
Section: Chapter Questions
Problem 13.98QE
See similar textbooks
icon
Related questions
Question

solve question 5

10.4. A reaction of stoichiometry A+B=Y + Z is found to be second order in A and zero order in B. Suggest a mechanism that is consistent with this behavior. 10.5. The rate of formation of the product of a reaction is found to give a nonlinear Arrhenius plot, the line being convex to the 1/T axis (i.e., the activation energy is higher at higher temperatures). Suggest a reason for this type of behavior. (Hint: For this and the following problem, consider the possibility of two parallel reactions and of two consecutive reactions having different activation energies.) 10.6. An Arrhenius plot is concave to the 1/T axis (i.e., it exhibits a lower activation energy at higher temperatures). Suggest a reason for this type of behavior. 10.7. Nitrogen pentoxide reacts with nitric oxide in the gas phase according to the stoichiometric equation N₂O5 + NO = 3NO₂ The following mechanism has been proposed. N₂O5NO₂ + NO3 NO₂ + NO3 N₂O5 NO + NO3 → 2NO₂ Assume that the steady-state treatment can be applied to NO3, and derive an equation for the rate of consumption of N₂O5.
Transcribed Image Text:10.4. A reaction of stoichiometry A+B=Y + Z is found to be second order in A and zero order in B. Suggest a mechanism that is consistent with this behavior. 10.5. The rate of formation of the product of a reaction is found to give a nonlinear Arrhenius plot, the line being convex to the 1/T axis (i.e., the activation energy is higher at higher temperatures). Suggest a reason for this type of behavior. (Hint: For this and the following problem, consider the possibility of two parallel reactions and of two consecutive reactions having different activation energies.) 10.6. An Arrhenius plot is concave to the 1/T axis (i.e., it exhibits a lower activation energy at higher temperatures). Suggest a reason for this type of behavior. 10.7. Nitrogen pentoxide reacts with nitric oxide in the gas phase according to the stoichiometric equation N₂O5 + NO = 3NO₂ The following mechanism has been proposed. N₂O5NO₂ + NO3 NO₂ + NO3 N₂O5 NO + NO3 → 2NO₂ Assume that the steady-state treatment can be applied to NO3, and derive an equation for the rate of consumption of N₂O5.
Expert Solution
steps

Step by step

Solved in 2 steps with 3 images

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Knowledge Booster
Rate Laws
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry: Principles and Practice
Chemistry: Principles and Practice
Chemistry
ISBN:
9780534420123
Author:
Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:
Cengage Learning
Chemistry for Engineering Students
Chemistry for Engineering Students
Chemistry
ISBN:
9781337398909
Author:
Lawrence S. Brown, Tom Holme
Publisher:
Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:
9781938168390
Author:
Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:
OpenStax
Chemistry: The Molecular Science
Chemistry: The Molecular Science
Chemistry
ISBN:
9781285199047
Author:
John W. Moore, Conrad L. Stanitski
Publisher:
Cengage Learning
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
Chemistry
ISBN:
9781337399074
Author:
John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:
Cengage Learning
SEE MORE TEXTBOOKS