16) The reaction (C2H5)2(NH2) + 12 (C2H5)2(N2) + 2HI Expt Initial(C2H5)2(NH2) mol L-1 Initial 12 mol L-1 gives the following data. Initial rate of formation of (C2H5)2(N2) mol L-1min1 1 0.015 0.015 3.15 x 10-1 2 0.015 0.045 9.45x 10-1 3 0.030 0.045 18.9 x 10-1 a) Determine the order of the reaction with respect to each reactant. Explain how you arrived at each answer. (Show your method) b) What is the overall order of the reaction? c) Write the rate law expression.
16) The reaction (C2H5)2(NH2) + 12 (C2H5)2(N2) + 2HI Expt Initial(C2H5)2(NH2) mol L-1 Initial 12 mol L-1 gives the following data. Initial rate of formation of (C2H5)2(N2) mol L-1min1 1 0.015 0.015 3.15 x 10-1 2 0.015 0.045 9.45x 10-1 3 0.030 0.045 18.9 x 10-1 a) Determine the order of the reaction with respect to each reactant. Explain how you arrived at each answer. (Show your method) b) What is the overall order of the reaction? c) Write the rate law expression.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
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![16) The reaction (C2H5)2(NH2) + 12 (C2H5)2(N2) + 2HI gives the following data.
Expt
Initial(C2H5)2(NH2)
mol L-1
Initial 12
mol L-1
Initial rate of formation of
(C2H5)2(N2) mol L-1min-1
1
0.015
0.015
3.15 x 10-1
2
0.015
0.045
9.45x 10-1
3
0.030
0.045
18.9 x 10-1
a) Determine the order of the reaction with respect to each reactant. Explain how
you arrived at each answer. (Show your method)
b) What is the overall order of the reaction?
c) Write the rate law expression.
d) Calculate the rate constant, k and provide the proper units.
e) If (C2H5)2(N2) is formed at a rate of 9.45 M/s in experiment 3, what is the rate of
appearance of HI?
f) In experiment 3, assuming it goes to completion, if all of [(C2H5)2(NH2) ] is
reacted, what would be the amount of 12 remaining?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F413b1069-9f84-4cfe-9d59-00ddc869e16f%2Fc86b2825-dc2c-47aa-9c4e-76fc669ecde1%2Fa9yg5af_processed.jpeg&w=3840&q=75)
Transcribed Image Text:16) The reaction (C2H5)2(NH2) + 12 (C2H5)2(N2) + 2HI gives the following data.
Expt
Initial(C2H5)2(NH2)
mol L-1
Initial 12
mol L-1
Initial rate of formation of
(C2H5)2(N2) mol L-1min-1
1
0.015
0.015
3.15 x 10-1
2
0.015
0.045
9.45x 10-1
3
0.030
0.045
18.9 x 10-1
a) Determine the order of the reaction with respect to each reactant. Explain how
you arrived at each answer. (Show your method)
b) What is the overall order of the reaction?
c) Write the rate law expression.
d) Calculate the rate constant, k and provide the proper units.
e) If (C2H5)2(N2) is formed at a rate of 9.45 M/s in experiment 3, what is the rate of
appearance of HI?
f) In experiment 3, assuming it goes to completion, if all of [(C2H5)2(NH2) ] is
reacted, what would be the amount of 12 remaining?
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