18. Which carbanion is the most stableA. methyl carbanion (CH3-)B. ethyl carbanion (CH3CH2-)C. isopropyl carbanion ((CH3)2CH-)D.Chloromethyl carbanion (CICH2-)19. Which structural effect best explains the observed trend below:Compound C-CI bond length (A)1.781.771.76H3C-CICIH₂C-CICl₂HC-CIFH₂C-CI1.76A. resonance B. C-H hyperconjugation C. Inductive effect D. steric effect20. Assuming that each methyl/hydrogen 1,3-diaxial interaction destabilizes themethyl substituted cyclohexane by 0.9 kcal/mole; then what is the energydifference between 2 chair conformations of cis-1,3-dimethylcyclohexane.A. 0.9 kcal/molB. 1.8 kcal/molC. 2.7 kcal/molD. 3.6 kcal/mol

Dear student, since you have asked multiple questions but according to guidelines we will solve 1st…

Answered: 18. Which carbanion is the most stable…

18. Which carbanion is the most stable A. methyl carbanion (CH3-) B. ethyl carbanion (CH3CH2-) C. isopropyl carbanion ((CH3)2CH-) D.Chloromethyl carbanion (CICH2-)

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter22: Organic And Biological Molecules

Section: Chapter Questions

Problem 130AE: a. Use bond energies (see Table 3-3) to estimate H for the reaction of two molecules of glycine to...

See similar textbooks

Related questions

Q: 30 atoms of calcium weigh

Q: What does the overrun of icecream represent? Overrun % = weight of mixture (g) - weight of…

Q: Structure H₂ ATA He Name t Aldehyde or ketone? t t

Q: A 5 M solution of 100 mL of glucose contains how many grams of glucose, molecular mass = 180 g/mol?

A: Molarity is a concentration term for a solution. The molarity of the given solution is defined as…

Q: 2. Name any one chelating and extracting reagent you know other than oxine and briefly refer to its…

Q: Calculate ΔGinward. Is energy required for transport to happen? The cell is at 37°C. Membrane…

A: Given: Temperature of the cell = 37oC = 37 + 273 = 310 K Membrane potential = 0 V

Q: Suppose a 0.047M solution of oxalic acid (H2C2O4) is prepared. Calculate the equilibirum of C2O4^2-…

Q: I really need to know how to get to the expression for DeltaU using "the full differential", rather…

A: Equation for internal energy change for Vander waals equation

Q: Sorry, but how do you get from 5.55 : 11.2 : 1.38 to: 4: 8: 1 That doesn't make sense. They're…

A: To determine the molecular formula, we need to calculate moles and then mole ratio.

Q: Is methanol the same alcohol found in beer/wine/liquor? Yes. No. Your liver converts methanol first…

A: We are to discuss if methanol is same alcohol as that is found in beer, wine or liquor. Methanol is…

Q: Calculate the numbers of moles of O2 and H₂O that are required to react completely with 1.95 mol Fe…

Q: Part A It takes 54.0 J to raise the temperature of an 8.70 g piece of unknown metal from 13.0°C to…

Q: An aqueous solution made by dissolving 169 mg of an unkown compound (a nonelectrolyte) in enough…

Q: convert 0.750 moles of CuCl2 to mass in grams. b) 25cm3 of sodium hydroxide solution of unknown…

Q: Which of the following describes molarity? the number of moles in a solution plus one liter of…

A: The question is about definition of Molarity. This is Multiple choice question. There are 5 option…

Q: Write a Lewis structure for each of the following molecules. H3COCH3 (oxygen is between the two…

A: we need to draw the Lewis structure of H3COCH3

Q: Please answer this question as fast as you can please and tahnk you. I will afterwards write an…

A: In the titration we used a primary standard solution to determine the concentration of unknown…

Q: 33. The configuration of the compound below indicated by an asterisk is OH H HO CH2NH2 HO A. R D. I…

A: Draw an arrow starting from priority one and going to priority two and then to priority 3: If the…

Q: However, while helium and krypton are very close to ideal gases, they are not exactly ideal. What…

A: For gas atoms/molecules to be ideal, we consider that there is no intermolecular force of attraction…

Q: If 32 of He gas is filled into a ballon at 12 atm pressur ressure. if the Volume of the gas increase…

Q: The solubility of O2 in water is approximatly 0.00334 g L^-1 of water whe the teperature is 25 °C…

Q: Write the safety precautions for each chemical Dry ice Chloroform-D Limonene

A: We have to write the safety precautions of Dry ice , Chloroform D and Limonene Note: According to…

Q: chloral hydrate (C2H2Cl3O2) is a drug formerly used as a sedative and hypnotic. It is the compound…

A: We are to calculate the molar mass of chloral hydrate, C2H3Cl3O2 . Chloral hydrate is a drug used as…

Q: Complete the table by drawing the bond line structure, number of carbons in the parent chain, and…

A: we have to write the IUPAC name, determine the number of carbons in the parent chain and draw the…

Q: 1.Name the following alkenes according to the IUPAC nomenclature rules. Determine if the…

A: There are 2 types of alkene on basis of the priority group- 1- (E)- alkene in which higher priority…

Q: According to the following reaction, how many grams of water are required for the complete reaction…

Q: For each of the species below, identify any cyclic conjugated system, then: A. Determine the number…

A: Answer: If a compound has 4nπ electrons it will be Anti-Aromatic, it means if a system contains 4, 8…

Q: We've spent quite a bit of time thinking about the interactions between atoms or molecules, one of…

A: Given the bond energy of 1 mol C-C bond = 348 kJ/mol We have to find the minimum frequency of…

Q: Determine the bond angle for H2CS Express your answer using three significant figures.

A: Steric number of H2CS is 3 so it is sp2 hybridized. Steric number = number of Sigma bond + number…

Q: Part Two: Nomenclature 1. Write the names for the following ionic compounds that contain Type I…

Q: Give the symbol for an element that is 1) a halogen. 2) an alkali metal. 3) a noble gas. 4) an…

A: -> In periodic table halogens are kept in 7A group. -> In periodic table alkali metal are kept…

Q: According to the following reaction, how many moles of oxygen gas are necessary to form 0.944 moles…

Q: The preparations of two aqueous solutions are described in the table below. For each solution, write…

A: Given,♦ 0.6 mol of KOH is added to 1.0 L of a 0.3 M HF solution .♦ 0.2 mol of HI is added to 1.0 L…

Q: This question requires that you work your answers on a scratch piece of paper. Once completed,…

Q: lonic compounds are formed when a metal reacts with a nonmetal. Which two elements combine to form…

A: Ionic compounds are formed between ion. Metals lose electron and form cation while non-metal accept…

Q: Complete the table below for calculating the molar mass of the ionic compound magnesium bromide .…

Q: MISSED THIS? Watch KCV: Limiting Reactant, Theoretical Yield, and Percent Yield, IWE: Limiting…

A: Iron(II) sulfide reacts with hydrochloric acid to form iron(II) chloride and hydrogen sulfide. The…

Q: I don't understand. It must be in a +3 state? Why? F has a -1 charge, that means it would have: 9p…

A: Answer: Metal M should be chosen from the ones given in option.

Q: A.What the units of the rated constants of first- and second-order reactions if the concentration…

A: To solve this problem we have to use the concept of chemical kinetics .

Q: Multiply or divide the following measurements. Be sure each answer you enter contains the correct…

A: Rule of significant digit-1) In non decimal number, 0 comes after non-zero not count in significant…

Q: When done correctly, the theoretical mass of NaCl remaining in the beaker at the end of the…

A: Given reaction NaHCO3(aq) + HCl(aq) ----> NaCl(aq) + CO2(g) + H2O(l) We are asked why NaCl…

Q: 3. consider the following addition reaction - two Possible Products and shown. will these foory in a…

Q: What volume of concentrated H2SO4 (18.OM) is required to prepare 550mL of 4.00M H2SO4 solution?

Q: A compound is 40.0% C, 6.70% H, and 53.3% O by mass. Assume that we have a 100.-g sample of this…

A: The percent composition of the compound is: C = 40.0 % H = 6.70 % O = 53.3 % by mass Total mass of…

Q: Determine the neutral formula unit for the compound formed from the ions NH and CO2-. formula unit:

Q: Ionic compounds are formed when a metal reacts with a nonmetal.

Q: Calculate ΔGinward. Is energy required for transport to happen? The cell is at 25°C. Membrane…

A: Given: Temperature of the cell = 25oC = 25 + 273 = 298 K Membrane potential = -60 mV

Q: Which is the most acidic molecule? A B SH o of O A B C C O

A: The strength of the acid can be determined by the stability of the conjugate base after the donation…

Q: From the following data, determine the reaction order and calculate the rate constant of t [CIO] (M)…

Q: One of the chair conformations of cis-1-bromo-3-methylcyclohexane is more stable than the other by…

Concept explainers

Alkanes and Cycloalkanes

Alkanes are saturated organic compounds which are made up of C and H atoms. Alkanes have the general formula of CnH2n+2. Alkane contains sp3 hybridized carbon atoms with four sigmas (σ) bonds & every hydrogen atom is connected with one of the carbon atoms. The size of the alkane could be determined by the number of carbon atoms located in it.

Question

18. Which carbanion is the most stable
A. methyl carbanion (CH3-)
B. ethyl carbanion (CH3CH2-)
C. isopropyl carbanion ((CH3)2CH-)
D.Chloromethyl carbanion (CICH2-)
19. Which structural effect best explains the observed trend below:
Compound C-CI bond length (A)
1.78
1.77
1.76
H3C-CI
CIH₂C-CI
Cl₂HC-CI
FH₂C-CI
1.76
A. resonance B. C-H hyperconjugation C. Inductive effect D. steric effect
20. Assuming that each methyl/hydrogen 1,3-diaxial interaction destabilizes the
methyl substituted cyclohexane by 0.9 kcal/mole; then what is the energy
difference between 2 chair conformations of cis-1,3-dimethylcyclohexane.
A. 0.9 kcal/mol
B. 1.8 kcal/mol
C. 2.7 kcal/mol
D. 3.6 kcal/mol

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

The bond dissociation energy to break 3 C-H bond(s) in 1 mole of glycerol (HOCH2CH(OH)CH2OH, see image below) molecules is H Н—с Н—с. H. H -C- H Single Bond H N H 432 411 346 N 386 305 167 459 358 201 142 C=C 602 C=0 799 C=C 835 C=0 1072 Multiple Bonds C=N 615 O=O 494 C=N 887 N=N 942 "All values in kJ/mol"
12. The combustion of what volume of ethanol, measured at 23°C and 765 mm Hg, would be required to heat 1727 g of water from 25°℃ to 78°C? (AH data table provided in anwer key) C₂H5OH (1) + 3 02 (8) → 2 CO2 (g) + 3 H₂O (1)
Which of the named compounds have correct structures? * „OH CH, ČH̟CH̟B1 Br I meta chlorotoluene II. bromomethyltoluene III. para bromophenol NH, OCH, „NO, IV. ortho nitroanisole V. 2,4,6-trichloroaniline A. I, II, IV B. I, III, IV C. I, IV, V D. II, III, V
16. What is the correct structure for (2S,5R)-2-fluoro-5-methylnonane? I a. I b. II c. III d. IV III L IF An
1A1: Integrate existing knowledge of ionic/covalent bonding, lone pairs, formal charge, valence, and Lewis structures to generate chemically-correct organic building blocks. Examine the given line-angle structure and redraw it, correcting all errors of structure (bonding, lone pairs, formal charge, valence, and the octet rule). 14 H3C. CI- H3C CH3 O H3C B-CH3 N-CH3 CH3
2. What mass of methane (CHa(9) 02(g) → CO2(9) + H20(g) AH°rxn = -890 %3D
?CaSO4+AlCl3→CaCl2+Al2(SO4)3 Whats ?
Pentaborane BgHg/s) burns vigorously in O2 to give B203(s) and H20). Calculate AHpxn for the combustion of 5.00 mol of B5H9. AH{B2031s)) = -1,273.5 kJimol AH{BsHgls)] = 73.2 kJ/mol AH(H200) = -285.8 kJ/mol Muitiple Choice - 22,700 kJ -45,400 kJ 45,400 kJ - 9,090 kJ - 8,790 kJ
ow.com/ilrn/takeAssignment/takeCovalentActivity.do?locator=assignment-take [References] The combustion of 0.1562 g benzoic acid increases the temperature of a bomb calorimeter by 2.54°C. Calculate the heat capacity of this calorimeter. (The energy released by combustion of benzoic acid is 26.42 kJ/g.) Heat capacity kJ/°C A 0.2186-g sample of vanillin (C8 Hg O3) is then burned in the same calorimeter, and the temperature increases by 3.26°C. What is the energy of combustion per gram of vanillin? Energy kJ/g Per mole of vanillin? Energy kJ/mol
What's More (A) Activity 2.1: Structural Isomerism Identification Directions: Identify what type of structural isomerism is being exhibited by each pair of compounds. Choose from the three most common types of isomerism (e.g. chain, position and functional isomerism). CH;CHCH,CH,CH3 1. CH;CH,CHCH,CH3 3. CH,-C-CH,CH,CH, CH3 CH3 CH,CH,CCH,CH, 2-Pentanone 3-Pentanorie 2-Methylpentane 3-Methylpentane CH3 CH,-C-CH3 CH-CH2-CH-CH, CH3-CH2-C CH3-C CH, 2-methylbutane 2, 2-dimethyipropane HO, --CH3 propanolc acid methyl ethanoabe
Reagents a. CeHsCHO b. NaOH, ethanol c. Pyrrolidine, cat. H* d. H2C=CHCN e. H30* f. LDA g. ELOC(=0)CO,Et h. BRCH2CH=CH2 Na* OEt, ethanol j. Br2, H* k. K* t-BuO 1. CH2(CO2Et)2 m. heat Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda). Submit Answer Try Another Version 1 Item attempt remaining
3. What monomer or monomers are needed to form the following polymer 4. Rank the following radicals in order of stability (4=least stable, 1= most stable) d 5. Rank the following C-H bonds in order of increasing bond strength (if any are the same state which ones) (1= weakest, 3= strongest) xol H H