2) Compare your calculated AH values with real "enthalpy of combustion" values using the links above. How do your results compare? What does this say about your method for estimating AH values?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter2: Polar Covalent Bonds; Acids And Bases
Section2.SE: Something Extra
Problem 22VC: cis-l, 2-Dichloroethylene and trans-1, 2-dichloroethylene are isomers, compounds with the same...
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3) Сна
H1
1
C - H + 20-0
(
H
H
во Bond brokeu
4 C-H bond
20=0 bond
C) AH = [BDE ´ of bonds breaking] - [BOE's of bonds formed)
DH = 4 x B.D.Ex (C-H) + 2x B-DEX (0-7)
= [4 (911) +2(9947 - 2(799)-9 (959)] kg/mol
-802 kg/mol
1
DJ molar mans of CH4=16-09 g/mol
-80215/md
16.09g/mo
AH in
Bond Formed
了
13
gas
g
AH = -sok)/g
P
-D
· 0=c=0 + 2 H-O-H
OH in F? /mol
mxm of CHq
Std enthalpy change
of formation, AH gas
Standard molar entropy,
Se
Gas properties
van der Waals' constants[10]
-74.6 kJ/mol[8]
Enthalpy of combustion AH-891 kJ/mol[⁹]
Heat capacity, Cp
186.3 J/(mol K)[8]
35.7 J/(mol K)[8]
2
a = 228.29 L² kPa/mol²
b = 0.04278 L/mol
Vapor pressure of liquid [edit]
Transcribed Image Text:3) Сна H1 1 C - H + 20-0 ( H H во Bond brokeu 4 C-H bond 20=0 bond C) AH = [BDE ´ of bonds breaking] - [BOE's of bonds formed) DH = 4 x B.D.Ex (C-H) + 2x B-DEX (0-7) = [4 (911) +2(9947 - 2(799)-9 (959)] kg/mol -802 kg/mol 1 DJ molar mans of CH4=16-09 g/mol -80215/md 16.09g/mo AH in Bond Formed 了 13 gas g AH = -sok)/g P -D · 0=c=0 + 2 H-O-H OH in F? /mol mxm of CHq Std enthalpy change of formation, AH gas Standard molar entropy, Se Gas properties van der Waals' constants[10] -74.6 kJ/mol[8] Enthalpy of combustion AH-891 kJ/mol[⁹] Heat capacity, Cp 186.3 J/(mol K)[8] 35.7 J/(mol K)[8] 2 a = 228.29 L² kPa/mol² b = 0.04278 L/mol Vapor pressure of liquid [edit]
2) Compare your calculated AH values with real
"enthalpy of combustion" values using the links above. How do your results compare? What
does this say about your method for estimating AH values?
Transcribed Image Text:2) Compare your calculated AH values with real "enthalpy of combustion" values using the links above. How do your results compare? What does this say about your method for estimating AH values?
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