2. For the following amines A and B, show all of the Hoffman elimination products. If one product is favored, please indicate it as the major product. B
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- XVI. Which of the two nitrogens (a or b) would be more basic (stronger base)? CONCISELY explain why. H ·N· of aQ6. Identify the interacting frontier orbitals that allow the conversion of the following amide resonance forms into each other and draw the corresponding curly arrow mechanism. Please, specify the interacting orbitals and the curly arrows describing both forward and backward process. H3C CH3 'N' H3C .CH33. For the following set of compounds, box the most basic and circle the least basic.
- 2. For the following amines A and B, show all of the Hoffman elimination products. If one product is favored, please indicate it as the major product. 8. IZ: A.Q6. Identify the interacting frontier orbitals that allow the conversion of the following amide resonance forms into each other and draw the corresponding curly arrow mechanism. Please, specify the interacting orbitals and the curly arrows describing both forward and backward process. H3C CH3 H3C + CH3 N. ZI[References) Draw the structure of the product obtained when this amine is treated with excess iodomethane and then heated with Ag,0 (Hoffman elimination). ball & stickv + labels • Consider E/Z stereochemistry of alkenes. • Draw only the elimination product, do not the leaving group. • In cases where there is more than one answer, just draw one.
- Rank the following in order of increasing basicity. соо coo" coo .coo3. Draw the mechanism of the following reaction. Include all lone pairs and formal charges. Br NaNH2 (xs), NH3 BrFill in the boxes in the problem below to complete the reaction. STEREOCHEMISTRY EXISTS IN EACH OF THESE AND ALL POTENTIAL STEREOISOMERS THAT CAN RESULT/REACT SHOULD BE SHOWN. Et 1. BH, 2. H,O,, NAOH H,O H2 Pd For this last reaction with H2/Pd. (a) circle any chiral products. (b) Is the product mixture optically active? Yes or No (circle one!)
- Draw the curved arrow mechanism for the reaction between (2R,3S)-3,5-dimethylhexan-2-ol and PCl3. Note the specific instructions for each box. Include nonzero formal charges and lone pairs of electrons on all appropriate atoms. Then answer the question about the mechanism.Answer the following problem.The picture below shows the transition state and reaction coordinate diagram for one step in a chemical change. Draw all the products of this step. Make sure to include all nonzero formal charges.