(3) HI does not undergo free radical addition with 1-butene, even in the presence of a peroxide. Please provide an explanation by analyzing the propagation steps if the same radical reaction occurred with HI. Besides the bond dissociation enthalpies in the appendix, the following approximate bond dissociate enthalpies might be useful to you: The component of C=C -310 kJ/mol CH3CH₂CH₂CH₂-Br CH3CH₂CH₂CH₂-I -290 kJ/mol (C-Br bond) -235 kJ/mol (C-I bond)
(3) HI does not undergo free radical addition with 1-butene, even in the presence of a peroxide. Please provide an explanation by analyzing the propagation steps if the same radical reaction occurred with HI. Besides the bond dissociation enthalpies in the appendix, the following approximate bond dissociate enthalpies might be useful to you: The component of C=C -310 kJ/mol CH3CH₂CH₂CH₂-Br CH3CH₂CH₂CH₂-I -290 kJ/mol (C-Br bond) -235 kJ/mol (C-I bond)
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter21: Benzene And The Concept Of Aromaticity
Section: Chapter Questions
Problem 21.44P
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