3. The ethyl acetate concentration in an alcoholic solution was determined by diluting a 10.00-mL sample to 100.0mL. A 20.00-mL portion of the diluted solution was refluxed with 40.00 mL of 0.04672М КОН:CH3COOC2H5 + OH° ®CH3COO¯ + C2H5OHAfter cooling, the excess OH¯ was back-titrated with3.41 mL of 0.05042 M H2SO4. Calculate the number of grams ofethyl acetate (88.11 g/mol) per 100 mL of the original sample.

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Answered: 3. The ethyl acetate concentration in…

Introductory Chemistry For Today

8th Edition

ISBN:9781285644561

Author:Seager

Publisher:Seager

Chapter7: Solutions And Colloids

Section: Chapter Questions

Problem 7.34E

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The Handbook of Chemistry and Physics (http://openstaxcollege.org/l/16Handbook) gives solubilities of the following compounds in grams per 100 mL of water. Because these compounds are only slightly soluble, assume that the volume does not change on dissolution and calculate the solubility product for each. (a) BaSiF6, 0.026 g/100 mL (contains SiF62- ions) (b) Ce(IO3)4, 1.5102 g/100 mL (c) Gd2(SO4)3, 3.98 g/100 mL (d) (NH4)2PtBr6, 0.59 g/100 mL (contains PtBr62- ions)
The ethyl acetate concentration in an alcoholic solution was determined by diluting a 10.00-mL sample to 100.00 mL. A 19.00-mL portion of the diluted solution was refluxed with 40.00 mL of 0.04601 M KOH: CH3 СОО С2H; + ОН — СH3 COO + C2H; ОН After cooling, the excess OH was back-titrated with 3.02 mL of 0.05056 M H2 SO4. Calculate the amount of ethyl acetate (88.11 g/mol) in the original sample in grams. Amount of ethyl acetate =
148. Addition of 50.00 mL of 2.238 m H2SO4 (solution density = 1.1243 g/mL) to 50.00 mL of 2.238 M BaCl2 gives a white precipitate. (a) What is the mass of the precipitate in grams? (b) If you filter the mixture and add more H2SO4 solution to the filtrate, would you obtain more precipitate? Explain.
1. A sample of pure sodium oxalate, Na2C2O4 , weighing 0.2856 g is dissolved in water, sulfuric acid is added, and the solution titrated at 70°C , requiring 45.12 mL of a KMNO4 solution. The end point is overrun and back-titration is carried out with 1.74 mL of a 0.1032 N solution of oxalic acid. Calculate the normality of the KMNO4 solution. Hint: A redox reaction is involed between oxalate and permanganate. Look at the changes in oxidation state by determining the balanced redox reaction: 5C20,2 + + 2MN2+ 2 Mn04 + 10H* → 10CO2 + 8H20
Precipitimetry The chloride in a 4.321-g food sample was precipitated through the addition of 50.00 mL of a standard AgNO3 solution (10.00 mL AgNO3 = 11.22 mL KSCN). The precipitate was coated with nitrobenzene and the mixture was diluted to 250.0 mL. A 50.00 mL aliquot was taken from the diluted solution and required 4.56 mL back titration with a %3D standard KSCN solution (22.33 mL KSCN = 0.9758 g AgNO3). %3D Formula Masses: AgNO3 = 169.87; CI = 35.45 Calculate the following: 1. Molar concentration of KSCN solution M %3D 2. Molar concentration of AgNO3 solution M %3D 3. % (w/w) chloride in the original sample =
4pts) 2.80g of a mixture of Barium Nitrate, Ba(NO3)2 (MM = 261.35 g/mol) and Potassium Bromide, KBr (MM-119.01 g/mol) was dissolved in 200 mL of hot H₂0. Enough Ammonium Phosphate, (NH4)3PO4 (MM = 149.12 g/mol), was added to the solution to precipitate ALL the Barium as Barium Phosphate, Ba3(PO4)2 (s) (MM = 601.93 g/mol). The precipitate was filtered, dried, and weighed to a constant mass of 1.83 g. Determine the percentage by mass of Potassium Bromide, KBr in the original mixture.
A 0.411 g sample of potassium hydrogen phthalate, KHC8H4O4 (molar mass = 204.22g/mol), is dissolved with 50.0 mL of deionized water in a 125mL Erlenmeyer flask. The sample is titrated to the phenolphthalein endpoint with 15.17 mL of a sodium hydroxide solution. What is the molar concentration of the NaOH solution? Express the molar concentration of NaOH to the correct number of significant figures.
1. Calcium in a sample solution is determined by atomic absorption spectroscopy (AAS). A stock solution of calcium is prepared by dissolving 1.834 g CaCl, 2H,0 in water and diluting to 1 litre. From this stock solution, the second stock solution is prepared by the dilution factor of 10. Three standard solutions of calcium are prepared from the second stock solution with the following dilution factor: 20 (first standard solution), 10 (second standard solution) and 5 (third standard solution). A blank solution is prepared as well. Absorbance signals of AAS are as follows: 1.5 (blank solution), 10.6 (first standard solution), 20.1 (second standard solution), 38.5 (third standard solution), 29.6 (sample solution). (Molar mass; Ca = 40.00 g mol-, CI = 35.45 g mol-, 0 = 16.00 g mol-', H = 1.00 g mol-1) a. Construct ONE (1) plot that could be used to represent the calibration curve. b. From the plot of Q1a, determine the amount of calcium in parts per million.
A 25.00mL wastewater sample was analyzed for its Mg2+ content using a standard gravimetric method. the sample was diluted to 3.00L and an 11.00mL aliquot was treated to precipitate magnesium as MgNH4PO4.6H2O using (NH4)2HPO4 as the precipitating agent. the precipitate was then filtered, washed, dried, and ignited resulting in a 0.1325mg Mg2P2O7 residue. How much Mg (in ppm) is present in the original sample
A mixture contains Na2CO3, NaOH and inert matter. A sample weighing 1.500 g requires 28.85 ml of 0.500N HCI to reach a phenolphthalein endpoint, and an additional 23.85 to reach a methyl orange endpoint.What are the percentages of Na2C03 and NaOH?
Five white, 500-mg uncoated ascorbic acid (AA) tablets with an average weight of 0.6152-g were pulverized in a mortar. A sample of the powdered ascorbic acid weighing 0.4700-g was placed in an iodine flask and was dissolved in 50-mL H2SO4 then 5-g of KBr was added to the resulting solution. The solution was titrated with 47.81-mL of 0.09640 N STD. KBrO3 to reach a faint yellow endpoint then 3-g KI and 5-mL Starch TS. The blue color solution is then titrated with 2.73-mL of 0.09123 N STD. Na2S2O3 to reach the disappearance of the blue iodostarch complex. MW: KBrO3 = 167.0 ; KIO3 = 214.0 ; Na2S2O3 = 158.11 ; C6H8O6 = 176.12 Compute the milligrams of pure AA per tablet from the assay. 293.3 mg 502.5 mg None of the choices 383.9 mg
Approximately 6 mL of conc. perchloric acid ( 72% ) was transferred to a bottle and diluted with about 1 liter of water. A sample containing 251.5 mg of primary standard Na2B4O7.10H2O (Fwt= 382g/mol) required 27.41 mL of the HClO4 solution to reach the methyl red end point. What is the molar concentration of the HClO4 solution? Na2B4O7.10H2O + HClO4 ------------> NaClO4 H2B4O7.10H2O

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