4. A flash chamber operating at 50 °C and 200 kPa is separating 1,000 kg moles/hr of a feed that is 30 mol % propane, 10 mol % n-butane, 15 mol % n-pentane, and 45 mol % n-hexane. Find the product compositions and flow rates. K-values for each chemical can be obtained using following equation. Constants for fitting are given in the attached table.

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Chapter33: Automated Methods Of Analysis
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Problem 33.8QAP
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4. A flash chamber operating at 50 °C and 200 kPa is separating 1,000 kg moles/hr of a feed that is
30 mol % propane, 10 mol % n-butane, 15 mol % n-pentane, and 45 mol % n-hexane. Find the
product compositions and flow rates. K-values for each chemical can be obtained using following
equation. Constants for fitting are given in the attached table.
= ari/T° +a7z/T+a7& +a, In p+a,2/p° +a„3/P
TABLE 2-3. Constants for fit to K values using Eq. (2-30)
Mean
Error
Сompound
Methane
-292,860
-600,076.875
8.2445
-8951
59.8465
1.66
Ethylene
7.90595
-84677 42.94594 0
2.65
Ethane
-687,248.25
7.90694
-88600
49.02654 0
1.95
Propylene
Propane
-923,484.6875 0
7.71725
-87871 47.67624 0
1.90
-970,688.5625 0
7.15059
-76984 0
6.90224
2.35
Isobutane
-1,166,846
7.72668
-92213 0
2.52
n-Butane
-1,280,557
7.94986
-96455 0
3.61
Isopentane -1,481,583
n-Pentane
7.58071
-93159 0
4.56
-1,524,891
7.33129
-89143 0
4.30
n-Hexane
-1,778,901
6.96783
-.84634 0
4.90
n-Heptane -2,013,803
6.52914
-.79543 0
6.34
n-Octane
-7646.81641 12.48457 -73152 0
7.58
n-Nonane
-2,551,040
5.69313
-67818 0
9.40
n-Decane
-9760.45703 13.80354 -71470 0
5.69
Note: Tis in R, and p is in psia
Source: McWilliams (1973)
Transcribed Image Text:4. A flash chamber operating at 50 °C and 200 kPa is separating 1,000 kg moles/hr of a feed that is 30 mol % propane, 10 mol % n-butane, 15 mol % n-pentane, and 45 mol % n-hexane. Find the product compositions and flow rates. K-values for each chemical can be obtained using following equation. Constants for fitting are given in the attached table. = ari/T° +a7z/T+a7& +a, In p+a,2/p° +a„3/P TABLE 2-3. Constants for fit to K values using Eq. (2-30) Mean Error Сompound Methane -292,860 -600,076.875 8.2445 -8951 59.8465 1.66 Ethylene 7.90595 -84677 42.94594 0 2.65 Ethane -687,248.25 7.90694 -88600 49.02654 0 1.95 Propylene Propane -923,484.6875 0 7.71725 -87871 47.67624 0 1.90 -970,688.5625 0 7.15059 -76984 0 6.90224 2.35 Isobutane -1,166,846 7.72668 -92213 0 2.52 n-Butane -1,280,557 7.94986 -96455 0 3.61 Isopentane -1,481,583 n-Pentane 7.58071 -93159 0 4.56 -1,524,891 7.33129 -89143 0 4.30 n-Hexane -1,778,901 6.96783 -.84634 0 4.90 n-Heptane -2,013,803 6.52914 -.79543 0 6.34 n-Octane -7646.81641 12.48457 -73152 0 7.58 n-Nonane -2,551,040 5.69313 -67818 0 9.40 n-Decane -9760.45703 13.80354 -71470 0 5.69 Note: Tis in R, and p is in psia Source: McWilliams (1973)
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