4. When 0.050 mol of NaOH is added to 0.100 mol of an unknown weak acid, the pH was found to be 4.2. Which of the following can be the acid? (A) Chlorous acid (B) Nitrous acid K₂=1 x 10-² K₁ = 4 x 104 K₁ = 6 x 10-5 10-8 (C) Benzoic acid (D) Hypochlorous acid K₂=4 × Ka
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- (c) Calculate the pH of 0.5 mol/L sodium hydrogen carbonate, NaHCO3. The Ka,1 of carbonic acid, H₂CO3, is 4.3 x 10-7. Нансез ENDCOHSOH(ag) + H2On + CeHsO (aq) + H3O*(a9) Ka= 1.12 x 10-10 (a) Phenol is a weak acid that partially dissociates in water according to the equation above. Write the equilibrium-constant expression for the dissociation of the acid in water. (b) What is the pH of a 0.75 M CaHsOH(ag) solution? (C) For a certain reaction involving CaHsOH(ag) to proceed at a significant rate, the phenol must be primarily in its deprotonated form, C3H5O (eg). In order to ensure that the CsHsOH(aq) is deprotonated, the reaction must be conducted in a buffered solution. On the number scale below, circle each pH for which more than 50 percent of the phenol molecules are in the deprotonated form (CoHsO (aq). Justify your answer. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 Justification: (d) CeHsOH(ag) reacts with NaOH(ag). Write a net ionic equation representing this reaction (aka: invasion equation). (e) What is the pH of the resulting solution when 30 mL of 0.40 M CSH5OH(aq) is added to 25 mL of 0.60 M NAOH. Show all work…You prepared 500 mL buffer solution that contains 0.50 moles monoprotic weak acid (HA) and 0.30 moles conjugate base (NaA). The solution has a pH of 4.20. (a) What is the Kp of the conjugate base, NaA? (b) What is the pH of the buffer solution after adding 400 mL of 0.30 M H,SO4? pH = pKa – log(THA), [A*]
- At 50 °C, the ion-product constant for H2O has the valueKw = 5.48 x 10-14. (a) What is the pH of pure water at50 °C? (b) Based on the change in Kw with temperature,predict whether ΔH is positive, negative, or zero for theautoionization reaction of water:2 H2O(l) ⇌ H3O+(aq) + OH-(aq)Determine the pH of (a) A 0.10 M CH3COOH solution (ICE) (b) A solution that is 0.10 M CH3COOH and 0.10 M CH3COONa. Ka for CH3COOH = 1.8 X 10-5.Determine the pH of each of the following solutions.(a) 0.246 M hydrocyanic acid (HCN) (weak acid with Ka = 4.9e-10).(b) 0.228 M propionic acid (weak acid with Ka = 1.3e-05).(c) 0.850 M pyridine (weak base with Kb = 1.7e-09).
- A 0.018 M solution of salicylic acid, HOC6H4CO2H, has the same pH as 0.0038 M HNO3solution. (a) Write an equation for the ionization of salicylic acid in aqueous solution. (Assume only the –CO2H portion of the molecule ionizes.) (b) What is the pH of solution containing 0.018 M salicylic acid? (c) Calculate the Ka of salicylic acid.The pH of an aqueous solution of 0.400 M hydrocyanic acid, (Ka (HCN) = 4.00 × 10-10) isنقطتان )2( The pH of a 1.00 M Solution -1 of Nitrous acid HNO2 (pKb =10.6) is
- The major component of vinegar is acetic acid, CH3COOH. Its Ka is 1.8 × 10-5 . One student used 1.000 M NaOH to titrate 25.00 mL vinegar. At the end point, 21.82 mL NaOH was used. (a) What is the concentration of CH3COOH in vinegar? (b) What is the pH of the solution at the end point? (c) What indicator(s) the student should use in this titration? Explain1. the temperature for each solution is carried out at approximately 297 K where Kw = 1.00 x 10 ^-14 (a) 0.20 g of hydrogen chloride (HCl) is dissolved in water to make 4.5 L of solution. What is the pH of the resulting hydrochloric acid solution? (b) 0.70 g of sodium hydroxide (NaOH) pellets are dissolved in water to make 3.0 L of solution. What is the pH of this solution ?Propionic acid, HC3H5O2, has Ka= 1.34 x 10–5. (a) What is the molar concentration of H3O+ in 0.15 M HC3H5O2 and the pH of the solution? (b) What is the Kb value for the propionate ion, C3H5O2–? (c) Calculate the pH of 0.15 M solution of sodium propionate, NaC3H5O2. (d) Calculate the pH of solution that contains 0.12 M HC3H5O2 and 0.25 M NaC3H5O2.