Answered: 48) Which of the following elements… | bartleby

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter10: Liquids And Solids

Section: Chapter Questions

Problem 68E

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Question

Ee.88.

48) Which of the following elements could be added to Si(s) to make a type semiconductor?
a) Ge
b) As
c) Sb
d) Sn
e) none of the above
47) Identify the solid that has the highest melting point?
a) H20(s)
b) C(s, diamond)
c) l(s)
d) NaCl(s)
e Kr(s)

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Aluminum metal crystallizes with a face-centered cubic unit cell. The volume of the cell is 0.0662 nm3. (a) What is the atomic radius of aluminum in cm? (b) What is the volume of a single aluminum atom? (c) What is the density of a single aluminum atom? (d) In face-centered cubic cell packing, the fraction of empty space is 26.0%. When this is factored in, what is the calculated density of aluminum?
MnO has either the NaCI type structure or the CsCI type structure (see Exercise 69). The edge length of the MnO unit cell is 4.47 10-8 cm and the density of MnO is 5.28 g/cm3. a. Does MnO crystallize in the NaCl or the CsCl type structure? b. Assuming that the ionic radius of oxygen is 140. pm, estimate the ionic radius of manganese.
Silicon carbide, SiC, is a very hard, high-melting solid. What kind of crystal forces account for these properties?
Outline a two-dimensional unit cell for the pattern shown here. If the black squares are labeled A and the white squares are B, what is the simplest formula for a compound based on this pattern?
At very low temperatures oxygen, O2, freezes and forms a crystalline solid. Which best describes these crystals? (a) ionic (b) covalent network (c) metallic (d) amorphous (e) molecular crystals
On the basis of the description given, classify each of these solids as molecular, metallic, ionic, network, or amorphous, and explain your reasoning. (a) A soft, slippery solid that has no definite melting point but decomposes at temperatures above 250 C; the solid does not conduct electricity (b) Violet crystals that melt at 114 C and whose vapor irritates the nose; neither the solid nor the liquid conducts electricity (c) Hard, colorless crystals that melt at 2800 C; the liquid conducts electricity, but the solid does not (d) A hard solid that melts at 3410 C; both the solid and the liquid conduct electricity
The structures of another class of ceramic, high-temperature superconductors are shown in figures a-d. a. Determine the formula of each of these four superconductors. b. One of the structural features that appears to be essential for high-temperature superconductivity is the presence of planar sheets of copper and oxygen atoms. As the number of sheets in each unit cell increases, the temperature for the onset of superconductivity increases. Order the four structures from lowest to the highest superconducting temperature. c. Assign oxidation states to Cu in each structure assuming Tl exists as Tl3+. The oxidation states of Ca, Ba, and O are assumed to be + 2, + 2, and 2, respectively. d. It also appears that copper must display a mixture of oxidation states for a material to exhibit superconductivity. Explain how this occurs in these materi.als as well as in the superconductor in Exercise 87.
Plot the following data and determine Hvap for magnesium and lithium. In which metal is the bonding stronger? Vapor Pressure (mm Hg) Temperature(C) Li Mg 1 750. 620. 10 890. 740. 100 1080. 900. 400 1240. 1040. 760 1310. 1110.

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