6. When working on your answers make sure to write each step for the synthesis of the product, clearly, show all reactants and conditions, and apply them in the correct order. 6.- C C NC CH3
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- 4. There are six steps in the mechanism below. Identify the basic moves in this complicat ed mechanism – one we will see next semester when we discuss carbonyl compounds. The point is that even complicated mechanisms can be broken down into simple terms and movements we recognize from the beginning of organic chemistry. Н. Н A. но B. н но он D. Он E. H. Н F. :o: Он6) Complete the following mechanism. (D and SN2) H Br. NaH "H: " 7) Complete the following mechanism. (D and SN2) H NaH "H: " Br. SN2 Good Nucleophile SN2 ether THFIn case of dihalide like problem 8.54 c. 1. my think is like this. at the first E2 reaction, the hydrogen on cyclohexyl will be participate because its carbon is more substituted. then second E2 reaction, there are no more hydrogen on left carbon. so hydrogen on right carbon will be partcipate. as a result, the product is double bond not triple bond. Why is this wrong and only form triple bond? 2. Is it impossible to make Sn2 reaction that NH2- is working as nucleophile?
- 1. For the reaction in Fig. 9 draw the curved arrows and the structure of the transition state. H to Figure 9: Draw curved arrows and the structure of TS H₂O محمد OO-H2. Draw all resonance structures for nitrobenzene and phenol below. Substituents on an aromatic ring can affect the rate of electrophilic aromatic substitution as well as the stereochemistry (ortho, meta, para) of the product. Briefly explain how this works. See Text: 15.10 (10th ed.) NO2 OHWhich rearrangement would the two example of carbocation below most likely undergo? a. Methyl shiftb. Hydride shiftc. Paradigm shiftd. Equilibrium shift
- 1. Consider the following reaction. CI EtOH OEt a. Provide a reasonable arrow-pushing mechanism for the following reaction, showing all steps and balancing all charges. b. Predict the stereochemistry of the final product(s). c. Label the electrophilic sites on the molecule and explain why only one of them undergoes substitution.5) For the following multi-step reaction involvling a carbocation Overall Transformation CH3 CH3 H-Ci: CH3.. rearrangement, draw mechanism each -C : arrows to show how intermediate is formed and fill in the blanks for the types of elementary 丰 steps that are involved in this overall Stepwise Mechanism transformation. H. CH3, CH3 Step 3: Formation (fill in the blank) What is the driving force for Step 2 in problem #5? H-Ci: H. H-CI: CH3 CH3 Step 1: Addition (fill in the blank) Step 2: Shift (fill in the blank)Synthesis - Drawing Saved Synthesize the following compound from cyclohexanol, ethanol, and any other needed reagents. он Part 1 out of 2 plnts Preparation of organometallic reagent: еВook Print References A B CH3CH2OH CH3 CH2MGB. draw structure ... Draw the intermediate product above and select the correct reagent for A. O Br, O NaBr O HBr O Select the correct reagent for B. O Mg O MgBr2 O MgI, O MgO Hin Soluti raw 11 e here to search
- 1. SN1 or SN2 2. Include major product and stereochemistry 3. Add detailed reaction mechanisms5. Provide a reasonable mechanism for the following reaction, clearly showing all intermediates leading to product formation.. НО. H3C H₂SO4 H₂O CH3 H2. For each of the following molecules, draw all possible products of an allylic bromination. .d 3. Can you think of an alkene that undergos allylic bromination to produce only 3 products (do not count stereoisomers as different products)?