A balanced chemical reaction that includes the heat change (released or absorbed AH) during the reaction is called the thermochemical reaction. For exothermic and endothermic reactions, the value of enthalpy change respectively is ΔΗ-0; ΔΗ-0 %3D ΔΗ < 0; ΔΗ > 0 ΔΗ > 0; ΔΗ -0 ( ΔΗ > 0; ΔΗ < 0 ( ΔΗ 0; ΔΗ <0

A balanced chemical reaction that includes the heat change (released or absorbed AH) during the reaction is called the thermochemical reaction. For exothermic and endothermic reactions, the value of enthalpy change respectively is ΔΗ-0; ΔΗ-0 %3D ΔΗ < 0; ΔΗ > 0 ΔΗ > 0; ΔΗ -0 ( ΔΗ > 0; ΔΗ < 0 ( ΔΗ 0; ΔΗ <0

World of Chemistry

7th Edition

ISBN:9780618562763

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter10: Energy

Section: Chapter Questions

Problem 29A

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When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?
9.31 A metal radiator is made from 26.0 kg of iron. The specific heat of iron is 0.449Jg1C1 . How much heat must be supplied to the radiator to raise its temperature from 25.0 to 5 5.0°C?
Consider the following reaction in a vessel with a movable piston. R(g)+T(g)X(g)As the reaction takes place, the piston loses 1072 J of heat. The piston moves down and the surroundings do 549 J of work on the system. What is E?
Combustion of table sugar produces CO2(g) and H2O( l). When 1.46 g table sugar is combusted in a constant-volume (bomb) calorimeter, 24.00 kJ of heat is liberated. a. Assuming that table sugar is pure sucrose, C12H22O11 (s), write the balanced equation for the combustion reaction. b. Calculate E in kJ/mol C12H22O11 for the combustion reaction of sucrose.
9.89 A sample of gas is 80.0% CH4 and 20.0% C2H6 by mass. What is the heat from the combustion of 1.00 g of this mixture? Assume the products are CO2 (g) and H2O (l).
How much heat is produced when loo mL of 0.250 M HCl (density, 1.00 g/mL) and 200 mL of 0.150 M NaOH (density, 1.00 g/mL) are mixed? HCl(aq)+NaO(aq)NaCl(aq)+H2O(l)H298=58kJ If both solutions are at the same temperature and the heat capacity of the products is 4.19 J/g C, how much will the temperature increase? What assumption did you make in your calculation?
In the “Chemistry in Focus” segment Firewalking: Magic or Science?, it is claimed that one reason people can walk on hot coals is that human tissue is mainly composed of water. Because of this, a large amount of heat must be transferred from the coals to change the temperature of the feet significantly. How much heat must be transferred to 100.0 g of water to change its temperature by 35 °C?
A 29.1-mL sample of 1.05 M KOH is mixed with 20.9 mL of 1.07 M HBr in a coffee-cup calorimeter (see Section 6.6 of your text for a description of a coffee-cup calorimeter). The enthalpy of the reaction, written with the lowest whole-number coefficients, is 55.8 kJ. Both solutions are at 21.8C prior to mixing and reacting. What is the final temperature of the reaction mixture? When solving this problem, assume that no heat is lost from the calorimeter to the surroundings, the density of all solutions is 1.00 g/mL, and volumes are additive.
Calculate the enthalpy change when 5.00 g of propane is burned with excess oxygen according to the reaction mg src=Images/HTML_99425-10-80AP_image001.jpg alt="" align="top"/>
The heat of neutralization, Hneut, can be defined as the amount of heat released (or absorbed), q, per mole of acid (or base) neutralized. Hneut for nitric acid is -52 kJ/mol HNO3. At 27.3C, 50.00 mL of 0.743M HNO3 is neutralized by 1.00 M Sr(OH)2 in a coffee-cup calorimeter. (a) How many mL of Sr(OH)2 were used in the neutralization? (b) What is the final temperature of the resulting solution? (Use the assumptions in Question 11.)
Determine whether the statements given below are true or false. Consider enthalpy (H). (a) It is a state property. (b) qreaction(atconstantP)=H=HproductsHreactants (c) The magnitude of H is independent of the amount of reactant. (d) In an exothermic process, the enthalpy of the system remains unchanged.

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