Please help with part J, H, I and J: Complete the following: Stereochemistry, enantio-, and regioselectivity are important.CrO3, H2SO4a)OHBromination of an alcohol (Sn2)typeEtO₂CCO₂Etb)b)d)H3COtypeNH2 a)b)H3COtypea)b)OHg)typeCNCIh)acetoneSwern OxidationtypetypeCO₂HtypeДоноi)Me3SICI,ImidazoleOSiMe3Et3N, CH2Cl2Brtypea) Mg°, THFBrj)b); H3O+H2SO4 (H+)MeOHOMetypetype

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a) OH type Bromination of an alcohol (Sn2) a) EtO₂C CO₂Et b) OH b) c) type NH2 a) CN c) b) H3CO H3CO

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter12: Chirality

Section: Chapter Questions

Problem 25CTQ

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Question

Please help with part J, H, I and J:

Complete the following: Stereochemistry, enantio-, and regioselectivity are important.
CrO3, H2SO4
a)
OH
Bromination of an alcohol (Sn2)
type
EtO₂C
CO₂Et
b)
b)
d)
H3CO
type
NH2 a)
b)
H3CO
type
a)
b)
OH
g)
type
CN
CI
h)
acetone
Swern Oxidation
type
type
CO₂H
type
Доно
i)
Me3SICI,
Imidazole
OSiMe3
Et3N, CH2Cl2
Br
type
a) Mg°, THF
Br
j)
b); H3O+
H2SO4 (H+)
MeOH
OMe
type
type

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Step 1: Organic reactions

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Step 2: Bromination of alcohols

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Step 3: Alkylation of malonate ester and formation of carboxylic acid

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Step 4: Conversion of amine to nitriles

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