A student dissolves a Jefferson nickel to make 100.00 mL of solution in a volumetric flask. The student takes a 5.00 mL5.00 mL aliquot of the first solution and dilutes it to make 100.00 mL100.00 mL of a second solution. The student places a sample of the second solution in a cuvette for analysis using spectrophotometry. The molarity of the copper solution in the cuvette was determined by spectrophotometric analysis to be 2.90×10−2 M Cu.2.90×10−2 M

A student dissolves a Jefferson nickel to make 100.00 mL of solution in a volumetric flask. The student takes a 5.00 mL5.00 mL aliquot of the first solution and dilutes it to make 100.00 mL100.00 mL of a second solution. The student places a sample of the second solution in a cuvette for analysis using spectrophotometry. The molarity of the copper solution in the cuvette was determined by spectrophotometric analysis to be 2.90×10−2 M Cu.2.90×10−2 M

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter4: Energy And Chemical Reactions

Section: Chapter Questions

Problem 120QRT

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Beakers (a), (b), and (c) are representations of tiny sections (not to scale) of mixtures made from pure benzene and pure water. Select which beaker gives proper representation of the result when the two pure substances are mixed.
A student dissolves a Jefferson nickel to make 100.00 mL of solution in a volumetric flask. The student takes a 5.00 mL aliquot of the first solution and dilutes it to make 100.00 mL of a second solution. The student places a sample of the second solution in a cuvette for analysis using spectrophotometry. The molarity of the copper solution in the cuvette was determined by spectrophotometric analysis to be 2.90 x 10-2 M Cu. Calculate the mass of copper in the Jefferson nickel used to make the first solution. Use the diagram to help visualize the dilution process. WE IN GOD TRUST 100 mL LIBERTY 200 5 mL 100 mL cuvette
A student dissolves a Jefferson nickel to make 100.00 mL of solution in a volumetric flask. The student takes a 5.00 mL aliquot of the first solution and dilutes it to make 100.00 mL of a second solution. The student places a sample of the second solution in a cuvette for analysis using spectrophotometry. The molarity of the copper solution in the cuvette was determined by spectrophotometric analysis to be 2.90×10−2 M Cu. Calculate the mass of copper in the Jefferson nickel used to make the first solution.
You are preparing a 100.0 mL standard solution needed for titration analysis. The NaOH (40 g/mol) pellets are measured to be 0.5341 g in a balance with acceptable uncertainty of +0.001 g. Mass of the pellets is recorded after taring the container. The pellets are put in a beaker and added with 50 ml distilled water measured by a graduated cylinder. The solution is then quantitatively transferred to a 100-mL volumetric flask with uncertainty of ±0.08 mL and diluted to a 100-mL mark. What is the concentration (M) of the solution and estimate its uncertainty by propagation? Assumption: There is no uncertainty in molar mass. Express your answer as C+/- u M.
In the Analytical Chemistry laboratory, one of the B.Sc student Ms. Fatma wanted to analyze the presence of Iron(II) ion in the water samples collected from Sohar Industrial Area in the Sultanate of Oman and analyzed by Spectrophotometric method. (1) 250.00 mL of this water sample (Solution A) known to contain unknown amount of FeSO4. She has diluted Solution A by a dilution factor 10 to make 250.00 mL solution, which she labeled Solution B. Using Spectrophotometer, she has measured the absorbance value (0.642) for Solution B at 508 nm using 1.00 cm cell (cuvet). The molar absorptivity value for Fe2* ion at 508 nm is ɛ508 = 30.8 M-1cm1. (i) What volume of the solution A did she require to make the 250.00 mL of Solution В? (ii) in (i)? What instrument should she use to transfer the volume of the Solution A calculated (ii) Concentration of FeSO4 in Solution B. (iv) Concentration of FeSO4 in Solution A. Mass of FeSO4 in Solution A (Show your calculation) (v)
0.3414 grams of sample (crushed aspirin tablet) was weighed and dissolved in 25 mL ethanol. This solution was transferred into a 100 mL volumetric flask and filled to the mark with deionized water. 20 mL of the solution was filtered through a 0.22 μm pore filter and 503 μL of the filtered sample solution was diluted so, that the final volume of the solution was 12 mL. This sample solution and calibration solutions with known concentration of acetyl salicylic acid (ASA) were injected (injection volume 20 μL) into a HPLC and the following peak areas were measured (expressed as averages from three separate chromatographic runs): Solution Cal 1 Cal 2 Cal 3 Cal 4 Cal 5 Sample Structure of ASA: C(ASA) (mg/L) 0 OH B 53.5 105.9 140.9 195.4 247.4 Average weight of the tablet was estimated as 591.9 mg. What is the mass of ASA in one tablet? Please give the answer with 4 significant digits. Be sure you present the result with units! Peak area (mA.s) 4995 9953 12941 17271 22179 10467.3
A NaOH solution was titrated using potassium hydrogen phthalate (KHP, 204.22 g/mL, 99.90% purity) and phenolphthalein as indicator. Four samples of the pattern of 0.7987, 0.8039, 0.8104 and 0.8365 grams were weighed. These consumed 38.29 mL, 38.29 mL, 38.51 mL, and 39.96 mL, respectively. Calculate: A) the average molarity of the base. B) the standard deviation of the molarity and the 95% confidence limits
To measure the blood Ca2+ concentration of a patient’s sample, 5.00 mL of blood was diluted to a total volume of 250.00 mL. A 10.00 mL portion of the diluted blood was further mixed with 40.00 mL of calcium dye solution and the final concentration of Ca2+ was determined to be 4.52 μM in the final solution. What’s the blood Ca2+ concentration for this patient? (Assume that volumes are additive)
During Lab 4, you are titrating a sample of new orange juice to determine its ascorbic acid (aka vitamin C) content. You have previously determined an experimental conversion factor of 0.26 mg ascorbic acid/mL dye using an ascorbic acid standard. After measuring out 5.16 mL of your orange juice sample and ~10 mL of 3% metaphosphoric acid to a graduated cylinder, you dilute the solution to 50.33 mL with DI water. You finally dispense 10.87 mL of the diluted solution into an Erlenmeyer flask, add 4 drops of HCl, and use 6.48 mL of dye to reach the equilibration point. How much ascorbic acid (mg) is in your concentrated orange juice sample? The molecular weight of ascorbic acid is 176.12 g/mol.
A 100 mg vitamin C tablet weighed 1.681 g. A student crushed the tablet and transferred 0.150 g of the crushed powder into a 100 mL volumetric flask, dissolved the powder in ~30 mL DI water, then filled the flask to the calibration line with DI water and mixed well to create Solution 1. The student then transferred 19.82 mL of Solution 1 into a 100 mL volumetric flask and diluted to the calibration line with DI water to create Solution 2. Calculate the expected concentration (in mM) of ascorbic acid in Solution 2. Hint: Remember that you are starting with a 100 mg vitamin C tablet.
You measure 1.5232 g of oxalic acid on an analytical balance, add it to a 250-mL volumetric flask and add deionized H2O to a final volume of 250.0 mL. You measure 15.0 mL of the H2C2O4 solution with a 100-mL graduated cylinder and add it to a 125-mL Erlenmeyer flask. Then you add two drops of the indicator, phenolphthalein, to the oxalic acid solution in the flask. You dispense the NaOH solution from the buret into the flask (while swirling the flask) until you reach the endpoint. At the endpoint, the solution in the flask turns light pink. You repeat the titration two additional times for a total of three trials. H2C2O4 (aq) + 2 NaOH (aq) --> Na2C2O4 (aq) + 2 H2O (l) (I) (II) (III) Volume of H2C2O4 used 15.00 mL 15.00 mL 15.00 mL Molarity H2C2O4 standard solution is 0.48 M how many Moles of NaOH are there in each trial?
A 0.2 g sample of NazC204 consumed 30.92 ml of KMN04 to reach the faint pink endpoint in the standardization of KMNO4 solution. This standardized solution was used to analyze the calcium in a milk sample (density = 1.21 8/mL) by permanganimetry. A 5.9 ml of the milk sample was diluted to 250.0 mL, and a 25.00 mL aliquot was treated with (NH4)2C204 to precipitate calcium as Cac,04+H2O. Digestion, filtration and addition of acid followed and during titration, 20.01 mL of standardized KMNO4 was consumed. Calculate the % Ca (W/w) of the milk sample analyzed. Express your answer in 2 decimal places. No need to include the unit. MM (g/mol): NazC204 = 134 ; Ca = 40.08 Pertinent redox reactions: NazC204 + 2H30* → H2C204 + 2H20 + 2Na* 2Mno4 + 5H2C204 + 6H30* → 2MN2- + 10CO2 + 14H20 Caco3 + 2H30* → Ca2- + CO2 (g) + 3H2O Ca2* + C2042 + H2O → CaC204+H2O(s) CaC204+H2O(s) + 2H30* – Ca2* + H2C204+ H20 Round your answer to 2 decimal places.