An ice cube at 0.0°C is slowly melting. What is the change in the ice cube’s entropy for each 5.80 g of ice that melts? Latent heat of fusion of ice is 333.7 J/g.
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An ice cube at 0.0°C is slowly melting. What is the change in the ice cube’s entropy for each 5.80 g of ice that melts? Latent heat of fusion of ice is 333.7 J/g.
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- (a) What is the change in entropy if you start with 100 coins in the 45 heads and 55 tails macrostate, toss them, and get 51 heads and 49 tails? (b) What if you get 75 heads and 25 tails? (c) How much more likely is 51 heads and 49 tails than 75 heads and 25 tails? (d) Dues either outcome violate the second law of thermodynamics?(a) What is the change in entropy if you start with 10 coins in the 5 heads and 5 tails macrostate, toss them, and get 2 heads and 8 tails? (b) How much more likely is 5 heads and 5 tails than 2 heads and 8 tails? (Take the ratio of the number of microstates to find out.) (c) If you were betting on 2 heads and 8 tails would you accept odds of 252 to 45? Explain Why or why not. Table 15.5 10Coin Toss MacrostateNumber of Microstates (W) Heads Tails 10 0 1 9 1 10 8 2 45 7 3 120 6 4 210 5 5 252 4 6 210 3 7 120 2 8 45 1 9 10 0 10 1 Total: 1024(a) On a winter day, a certain house loses 5.00108J of heat to the outside (about 500,000 Btu). What is the total change in entropy due to this heat transfer alone, assuming an average indoor temperature of 21.0C and an average outdoor temperature of 5.00C ? (b) This large change in entropy implies a large amount of energy has become unavailable to do work. Where do we find more energy when such energy is lost to us?
- (a) How much food energy will a man metabolize in the process of doing 35.0 kJ of work with an efficiency of 5.00%? (b) How much heal transfer occurs to the environment to keep his temperature constant? Explicitly show how you follow the steps in the Problem—Solving Strategy for thermodynamics found in Problem-Solving Strategies for Thermodynamics.An ideal gas is taken from an initial temperature Ti to a higher final temperature Tf along two different reversible paths. Path A is at constant pressure, and path B is at constant volume. What is the relation between the entropy changes of the gas for these paths? (a) SA SB (b) SA = SB (c) SA SBOf the following, which is not a statement of the second law of thermodynamics? (a) No heat engine operating in a cycle can absorb energy from a reservoir and use it entirely to do work, (b) No real engine operating between two energy reservoirs can be more efficient than a Carnot engine operating between the same two reservoirs, (c) When a system undergoes a change in state, the change in the internal energy of the system is the sum of the energy transferred to the system by heat and the work done on the system, (d) The entropy of the Universe increases in all natural processes, (e) Energy will not spontaneously transfer by heat from a cold object to a hot object.
- A 65-g ice cube is initially at 0.0C. (a) Find the change in entropy of the cube after it melts completely at 0.0C. (b) What is the change in entropy of the environment in this process? Hint: The latent heat of fusion for water is 3.33 105 J/kg.A copper rod of cross-sectional area 5.0 cm2 and length 5.0 m conducts heat from a heat reservoir at 373 K to one at 273 K. What is the time rate of change of the universe's entropy for this process?Assume a sample of an ideal gas is at room temperature. What action will necessarily make the entropy of the sample increase? (a) Transfer energy into it by heat. (b) Transfer energy into it irreversibly by heat. (c) Do work on it. (d) Increase either its temperature or its volume, without letting the other variable decrease. (e) None of those choices is correct.
- A sample of a monatomic ideal gas is contained in a cylinder with a piston. Its stale is represented by the dot in the PV diagram shown in Figure OQ22.9. Arrows A through E represent isobaric, isothermal, adiabatic, and isovolumetric processes that the sample can undergo. In each process except D, the volume changes by a factor of 2. All five processes are reversible. Rank the processes according to the change in entropy of the gas from the largest positive value to the largest-magnitude negative value. In your rankings, display any cases of equality.(a) In reaching equilibrium, how much heat transfer occurs from 1.00 kg of water at 40.0C when it is placed in contact with 1.00 kg of 20.0C water in reaching equilibrium? (b) What is the change in entropy due to this heat transfer? (c) How much work is made unavailable, taking the lowest temperature to be 20.0C ? Explicitly show how you follow the steps in the Problem-Solving Strategies for Entropy.(a) What is the hot reservoir temperature of a Carnot engine that has an eficiency of 42.0% and a cold reservoir temperature of 210C ? (b) What must the hot reservoir temperature be for a real heat engine that achieves 0.700 of the maximum eficiency, but still has an efficiency of 42.0% (and a cold reservoir at 27.0C )? (c) Does your answer imply practical limits to the efficiency of car gasoline engines?
