Answered: Br CI CI 162 209 NH₂ 1,4-dibromobutane…

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Br CI CI 162 209 NH₂ 1,4-dibromobutane NaH, DMSO, rt, 52% AICI3, DCM, 5 to 15 °C 88% from 208 P

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter19: The Chemistry Of The Main-group Elements

Section: Chapter Questions

Problem 91QRT

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Concept explainers

Group 15 elements

The elements of group 15 are phosphorus, nitrogen, bismuth antimony, and arsenic. The most abundant element which is present in the air is nitrogen and the percentage of nitrogen present in the air is 78%. In the free state, the elemental nitrogen is present as diatomic gas (N2). In the organic matter obtained from plants and animals, phosphorus is the dominant element present. In nucleic acids, phosphate groups are present. Phosphates are also found in teeth and bones. The other elements arsenic, bismuth, and antimony are found as sulfides. Arsenopyrite, bismuth glance, and stibnite are examples of sulfides of arsenic, bismuth, and antimony respectively.

Question

Br
CI
162
CI-
209
NH₂
1,4-dibromobutane
NaH, DMSO, rt, 52%
AICI 3, DCM, 5 to 15 °C
88% from 208
P

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