C13H180 8 7 (O 5 PPM 2 (singlet) 2 (quartet) 1 (septet) 3 2 3 (triplet) 6 (doublet)

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter19: Nuclear Magnetic Resonance Spectroscopy
Section: Chapter Questions
Problem 19.37QAP: From the proton spectrum given in Figure 19-45, determine the structure of this compound, a commc...
icon
Related questions
Question

(40) Which of the following structures corresponds to the attached 1H-NMR spectrum?

C13H180
8
7
G-G-CH₂
L-CM₂
PPM
TABLE 13.1 Approximate Values of Chemical Shifts for ¹H NMR
Type of proton
(CH),Si
-CH₂
-CH₂-
-CH-
-CH₂
6
-C-C-H
0.9
1.3
1.4
1.7
Approximate chemical shift (ppm) Type of proton
-H
2.1
2.3
2.4
5
R-O-CH₂
3.3
R-C-CH, 4.7
R
R-C-Ç-H
2
(singlet)
5.3
LH
B-C-H
a-c-H
F-CH
RNH₂
ROH
Агон
(septet)
Lon
"The values are approximate because they are affected by neighboring substituents.
3
2
(quartet)
9.0-10
2.5-4
Approximate chemical shift (ppm)
6.5-8
2.5-4
2
I
variable, 1.5-4
variable, 2-5
variable, 4-7
3
(triplet)
variable, 10-12
6
(doublet)
Transcribed Image Text:C13H180 8 7 G-G-CH₂ L-CM₂ PPM TABLE 13.1 Approximate Values of Chemical Shifts for ¹H NMR Type of proton (CH),Si -CH₂ -CH₂- -CH- -CH₂ 6 -C-C-H 0.9 1.3 1.4 1.7 Approximate chemical shift (ppm) Type of proton -H 2.1 2.3 2.4 5 R-O-CH₂ 3.3 R-C-CH, 4.7 R R-C-Ç-H 2 (singlet) 5.3 LH B-C-H a-c-H F-CH RNH₂ ROH Агон (septet) Lon "The values are approximate because they are affected by neighboring substituents. 3 2 (quartet) 9.0-10 2.5-4 Approximate chemical shift (ppm) 6.5-8 2.5-4 2 I variable, 1.5-4 variable, 2-5 variable, 4-7 3 (triplet) variable, 10-12 6 (doublet)
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 4 steps with 4 images

Blurred answer
Knowledge Booster
Quality Assurance and Calibration Methods
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning