10. The data below are for the reaction: 2 NO₂ (g) + F₂ (g) → 2 NO₂F (g) [NO₂] (M) 0.100 0.200 0.200 0.400 0.200 [F₂] (M) 0.100 0.100 0.200 0.400 0.400 Initial rate (M/s) 0.026 0.051 0.103 0.411 see part c a. Write the rate law for this reaction. b. Determine the rate constant for this reaction. Pay attention to units. c. Predict the initial rate of the reaction when [NO₂] = 0.200 M and [F₂] = 0.400 M.

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 12PS: The reaction 2 NO(g) + 2 H2(g) N2(g) + 2 H2O(g) was studied at 904 C, and the data in the table...
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10. The data below are for the reaction:
2 NO₂ (g) + F₂ (g) → 2 NO₂F (g)
[NO₂] (M)
0.100
0.200
0.200
0.400
0.200
[F₂] (M)
0.100
0.100
0.200
0.400
0.400
Initial rate (M/s)
0.026
0.051
0.103
0.411
see part c
a. Write the rate law for this reaction.
b. Determine the rate constant for this reaction. Pay attention to units.
c. Predict the initial rate of the reaction when [NO₂] = 0.200 M and [F₂] =
0.400 M.
d. The mechanism of the reaction is suggested as two steps:
NO₂+ F2 → NO₂F + F
(fast)
NO₂+ F→→ NO₂F
(slow)
Is your rate law consistent with this mechanism? Explain your answer, making
any changes necessary to create consistency.
Transcribed Image Text:10. The data below are for the reaction: 2 NO₂ (g) + F₂ (g) → 2 NO₂F (g) [NO₂] (M) 0.100 0.200 0.200 0.400 0.200 [F₂] (M) 0.100 0.100 0.200 0.400 0.400 Initial rate (M/s) 0.026 0.051 0.103 0.411 see part c a. Write the rate law for this reaction. b. Determine the rate constant for this reaction. Pay attention to units. c. Predict the initial rate of the reaction when [NO₂] = 0.200 M and [F₂] = 0.400 M. d. The mechanism of the reaction is suggested as two steps: NO₂+ F2 → NO₂F + F (fast) NO₂+ F→→ NO₂F (slow) Is your rate law consistent with this mechanism? Explain your answer, making any changes necessary to create consistency.
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d. The mechanism of the reaction is suggested as two steps:
NO2+ F2 → NO₂F + F
(fast)
NO₂+ F→ NO₂F
(slow)
Is your rate law consistent with this mechanism? Explain your answer, making
any changes necessary to create consistency.
Transcribed Image Text:d. The mechanism of the reaction is suggested as two steps: NO2+ F2 → NO₂F + F (fast) NO₂+ F→ NO₂F (slow) Is your rate law consistent with this mechanism? Explain your answer, making any changes necessary to create consistency.
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