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- Reagents a. C6H5CHO b. NaOH, ethanol h. BrCH2CH=CH2 i. Na* OEt, ethanol j. Br2, H* k. K* t-BuO c. Pyrrolidine, cat. H* d. H2C=CHCN e. H3O* f. I. CH2(CO2ET)2 -CH2CH2CN LDA m. heat g. ELOC(=0)CO2ET Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).a. Which of the following alcohols can be oxidized to carboxylic acid? b. Which is resistant to oxidation? c. Which produces unsymmetrical ketone after oxidation? d. Which produces a tri-substituted alkene as the sole product in elimination reaction?Show how to convert cyclohexanol to these compounds. a. Cyclohexene b. Cyclohexane c. Cyclohexanone d. Bromocyclohexane
- Synthesize each compound from cyclohexanol using any other organic or inorganic compounds. a. ہیں۔ بھی مله C. OH d.1. Name one product of the nitration of butane. Use IUPAC nomenaclature. 2. Which primary alcohol can be oxidized to form propanoic acid? 3. Which substitution reaction of a hydrogen in benzene will turn a blue litmus red? A. acylationB. halogenationC. alkylationD. all of the aboveE. none of the above 4. Heptyl phenyl ketone was formed from the Friedel-Crafts acylation of benzene with an acyl chloride. What is the IUPAC name of the original acyl chloride? 5. How many isomers are there Of C6H14? 6. Aside from a halogenated alkane, what other product results from the bromination of hexane? Write the formula 7. How many carbon atoms are there in 2,5-diethyl-7-methylbicyclo[2.2.1]heptane? 8. R-MgX and CO2 are reacted to form isobutyric acid. What is R? Use IUPAC nomenclature of the substituent. 9. From which cycloalkene can heptanoic acid be formed from through oxidative cleavage? Use IUPAC name. 10. The catalytic hydrogenation of a benzene will result to this cycloalkaneGive the structure corresponding to each IUPAC name. a. 2-methoxypropane b. cyclobutyl ethyl ether c. 1-ethoxy-2-ethylcyclohexane d. butyl chloride e. 2-methylcyclohexanethiol f. 1-ethyl-2-fl uorocyclobutane
- Cyclopentanone is treated with chlorine (Cl2) in the presence of acid (H*). What product is formed? A. Chlorocyclopentane B. 1-chloro-1-hydroxycyclopentane C. 2-chlorocyclopentanone D. 3-chlorocyclopentanoneDraw the organic product(s) formed when CH3CH₂CH₂OH is treated with each reagent. a. H₂SO4 d. HBr g. TsCl, pyridine b. NaH h. [1] NaH; [2] CH₂CH₂Br e. SOCI₂, pyridine f. PBr3 c. HCI + ZnCl₂ Hint: NaH deprotonates the alcohol forming an alkoxideReagents available f. PBr3 g. Mg, ether a. CH3CH,COCH b. C6H5 COCI c. AlCl3 d. NaBH₁, ethanol e. H₂SO4, dil am h. H₂SO4, conc i. SOCI₂ j. C6H5 CN
- 7. Enols react as a. Electrophiles.....alkenes b. Electrophiles....alkanes c. Nucleophiles...alkenes d. Nucleophiles...alkanes in the same way that 8. Acylation of enolate ions proceeds by a a. E1 b. E2 C. SN1 d. SN2 c. Anhydride d. Beta-ketoacid | 9. The following molecule would be classified as a a. Alpha-ketoamide b. Beta-aldobase do. mechanism. HOStarting with cyclohexanone, show how to prepare these compounds. In addition to the given starting material, use any other organic or inorganic reagents as necessary. a. Cyclohexanol b. Cyclohexene c. cis-1,2-Cyclohexanediol d. 1-Methylcyclohexanol e. 1-Methylcyclohexene f. 1-Phenylcyclohexanol g. 1-Phenylcyclohexene h. Cyclohexene oxide i. trans-1,2-CyclohexanediolHow many moles of Bra are required to completely halogenate the alkene?A. One moleB. Two molesC. Three molesD. Four moles What is the expected arrangement of the bromine atoms relative to each other amongthe carbon involved in pi bonding?A. anti-conformationB. syn-conformationC. trans-configurationD. cis-configuration What happens to bromine when it is adjacent to an alkene during a chemical reaction?A. Bromine becomes stable. (? kasi before brown siya/acidic tas naging colorless? Jk ewan)B. Bromine becomes polarized.C. Bromine becomes hybridized.D. Bromine becomes acidic. The relative arrangement of bromine atoms in the product is primarily due to:A. ElectronegativityB. RepulsionC. Hydrogen bondingD. Atomic weightWhat is your observation after the reaction?A. A yellow flame is produced.B. Bromine water decolorizes.C. The alkene becomes denser.D. A brown precipitate forms.