draw the product (e) DMP, CH2CI2РСС, СН-Cl2Pyridiniumchlorochromate inmethylene chloridesolventAco OAc-OAcOAc =1. DMSO, (COCI)22. Et,NDimethylsulfoxide &oxalyl chloride, thentriethylamineDess-Martin Periodinane(DMP)in methylene chloridesolvent

Answered: Image /qna-images/answer/b569c3a7-2a54-4637-b400-05fed3df17ba.jpg

(e) DMP, CH2CI2 РСС, СН2CI2 Pyridinium chlorochromate in Aco OAc -OAc methylene chloride solvent OAc = 1. DMSO, (COCI)2 2. Et,N Dimethylsulfoxide & oxalyl chloride, then triethylamine Dess-Martin Periodinane (DMP) in methylene chloride solvent

(e) DMP, CH2CI2 РСС, СН2CI2 Pyridinium chlorochromate in Aco OAc -OAc methylene chloride solvent OAc = 1. DMSO, (COCI)2 2. Et,N Dimethylsulfoxide & oxalyl chloride, then triethylamine Dess-Martin Periodinane (DMP) in methylene chloride solvent

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Related questions

Q: Classify the following as physical or chemical change: Roses turning brown [ Choose ] When water fro...

A: Physical change : It is basically a reversible reaction. Chemical change : It cannot be reversed onc...

Q: calculate the theoretical yield of a reaction( in grams) between 5mmol N,N-diethylethanolamine and 5...

Q: For the n=4 shell, rank the sub shells in order from lowest to highest energy

A: The correct answer is given ?

Q: Menthol is a very cool compound. If a sample of menthol is examined by UV spectroscopy, what would y...

A: Given :- Menthol compound which is a very cool compound, so here we have to find that what would we ...

Q: Place the best reagent in the bin for each of these reactions involving cyclohexylmethanol. Br Answe...

A: Answer: This question is best on chemical properties of primary alcohol.

Q: concentration o

Q: N. 'N. N. Z-

Q: From the following chemical equation: Cl2 F+ G+ H FeCl3 i) Draw the structure of F, G and H. ii) Bas...

Q: How does the concentration of a gas in solution change when the partial pressure of the gas above th...

Q: Why is the boiling point of 2-bromobutane lower than that of 1-bromobutane. Your answer should go be...

A: Boiling point can be defined as the temperature required for conversion of solid substance into liqu...

Q: What is the initial rate of the reaction in Experiment 4? Initial rate mol/(L · s)

A: Well, first step for the calculation is to determine the rate equation from the given experiments. F...

Q: Concentrated HBr is 48% HBr by mass and has a density of 1.50 g/mL.How many grams of concentrated s...

A: Given: Concentration of final solution = 1.50 M Volume of final solution = 750 mL = 0.750 L ...

Q: higher boiling point

Q: Initially 3.0 mol of nitrosyl bromide, NOBr, is placed in a 5.0 L container and allowed to come to e...

Q: A galvanic cell is powered by the following redox reaction: Cl,(g) + H,(g) + 2 OH (aq) → 2 Cl (aq) +...

A: Given : We have to write half reaction taking place at anode and cathode.

Q: percentage by mass

Q: Propose a pathway to synthesize 2-Methylpentane using: + 2Li t CuI+ CH3CH 2CH2CI CHg

Q: Acetic acid and ethanol react to form ethyl acetate and water, like this: HCH,CO,(aq)+C,H,OH(aq) C,H...

A: Answer: This question is based on the Le-chatalier's principle, according to which, on changing any ...

Q: At 500°C, and in the presence of a catalyst, steam (water vapour) reacts with carbon to give a mixtu...

A: Given: Steam reacts with carbon to give hydrogen and carbon monoxide. Initial temperature = 500 oC =...

Q: For the gas phase decomposition of hydrogen peroxide at 400 °C 2 H202 2 H20 + 02 the average rate of...

A: Since you have posted multiple questions, we are entitled to answer the first only.

Q: Nitrogen monoxide, NO, reacts with hydrogen to give nitrous oxide, N20, and water. 2NO(g) + H2 (g) →...

Q: DISCUSS THE FOLLOWING DIPOLE DIPOLE FORCES,ION-DIPOLE FORCES, DISPERSION FORCES, THE HYDROGEN BOND

A: Since you have posted multiple questions, we are entitled to answer the first ony.

Q: The aquation of tris(1,10-phenanthroline)iron(II) in acid solution takes place according to the foll...

A: Given :- Activation Energy = 126KJ/mol Rate constant at 30℃ = 9.8×10-3 min-1 To find :- Rate constan...

Q: ned: [NH3), M 1.03x10-2 5.15x10-3 1.29x10-3 773 2.58x10-3 seconds 442 662 Hint: It is not necessary ...

Q: 1. Fill in the blanks with the MAJOR organic product in the following reactions. OH H,SO4, 130°C HO,...

A: Major organic product are deduced by applying reasonable mechanism on substrate.

Q: A 3.750 g sample of the compound responsible for the odor of cloves (containing only C, H, and O is ...

Q: Diamond, lattice constant (a) = 0.3567 nm, shares the same crystal structure as Si, FCC with lattice...

A: X-ray diffraction is commonly used as a non-destructive method of studying carbon materials and oth...

Q: CH3 H;C =CH,CH3 ČH3 CH3 ČH3

Q: Step 1: O3 + HO — но2+ 02 Step 2: HO2 + O — но +02 Which species is an intermediate? OH C O HO2 O 03

Q: Make a suggestion of the reagents required to produce the following:

A: The functional groups of a molecule are a key component that plays a significant role in providing t...

Q: Given the following equilibrium constants at 700K, 2 N2O(g) (double arrow) 2 N2 (g) + O2(g) K1 = 8....

A: The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical eq...

Q: 8.00 mL of 9.00 x 10-3 M Fe(NO3)3 (9.00 times 10 to the minus 3rd power M F e (NO3)3) is added to 5....

A: Volume of Fe(NO3)3 = 8ml Concentratio of Fe(NO3)3 = 9×10-3M Volume of KSCN = 5ml Concentratio of KSC...

Q: 3. The following mineral analysis was reported for a water sample taken from a local NJ well. Determ...

Q: How many molecules of C2H6 are there in 21.4 g of C2H6?

A: Given that, 21.4 g of ethane, C2H6. We have to calculate the number of molecules in it.

Q: Difference between minor and major constituent

A: A question based on solution that is to be accomplished.

Q: The compound Pb(NO2)2 is an ionic compound. What are the ions of which it is composed? Cation formul...

A: The given compound is Pb(NO2)2. The ions in the given compound are Pb2+ and 2NO2-.

Q: The reaction below reaches equilibrium in a closed reaction vessel. What is the effect of adding an ...

A: The correct option is:

Q: If 100.0 g of butane is combusted with the aid of 200.0 g Oxygen gas? C4H10 + 02 →CO2 + H2O , which ...

A: In order to determine the limiting reagent we have to see the amount of reactant present in lesser m...

Q: The reaction of nitrogen dioxide with fluorine 2 NO2 + F2-2 NO,F is first order in NO, and first ord...

A: The sum of the exponent term in the rate law for a chemical reaction is known as the order of the re...

Q: Benzene and toluene form an ideal solutions. At 900 C, the vapor pressure of pure benzene is 1.326 a...

Q: Calculate the amount of water (in grams) that must be added to each of the following substances to p...

A: The given data is as follows: (a) The mass of urea = 2.50 g The mass percent of the solution = 13.5 ...

Q: 1. Complete the table Isotope Mass (amu) Relative Abundance (%) Silicon- 28 27.97693 92.21 Silicon- ...

A: For this problem We have to complete the given table based on abundance of isotopes.

Q: 9. Consider the unbalanced chemical reaction equation H3O+ +I+MnO4 → I2 + MnO2 + H2OWhat is the bala...

Q: what are the cell notations for the table 1?

A: While writing a cell notation we write anode or oxidation and in right side we write reduction react...

Q: 11% O Mon File Edit View History Bookmarks Profiles Tab Window Help Chrome O S550 Mustan (6 unread) ...

A: Given, Gaseous ammonia react with oxygen gas to produce nitrogen monoxide and water vapor, the moles...

Q: m the following reaction, ОН OH H,SO4 A + B Draw a correct structure of A and B.

Q: Tools Add-ons Help Last edit was 4 minutes ago 4. Cu AgNO,- Cu(NO,)2 Ag Balanced Equation: Reaction ...

A: Balancing a chemical reaction involves making the number atoms equal on both sides of reaction

Q: rovide one alkyl halide of your choice and discuss its structure, nomenclature (systematic and commo...

A: Given : We have to tell one alkyl halide and its preparation as well as its application.

Q: a) What is the meaning of the following symbols? i. ii. E ii. A b) State TWO (2) conditions necessar...

A: a) The meaning of the given symbol is, i) The given symbol is called psi. It indicates the wave func...

Q: INT: This problem has 2 conversions. Convert the given to moles, then convert the moles to the final...

A: Given : Volume of CH4 = 28.8L

Question

draw the product

(e) DMP, CH2CI2
РСС, СН-Cl2
Pyridinium
chlorochromate in
methylene chloride
solvent
Aco OAc
-OAc
OAc =
1. DMSO, (COCI)2
2. Et,N
Dimethylsulfoxide &
oxalyl chloride, then
triethylamine
Dess-Martin Periodinane
(DMP)
in methylene chloride
solvent

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Reaction with DMP gives aldehyde

VIEW

Reaction with PCC gives aldehyde

VIEW

Reaction with DMSO gives aldehyde

VIEW

Step by step

Solved in 3 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

https://session.masteringchemistry.com/myct/itemView?assignmentProblemID=191107816&offset=prev#
(weo pentane it consists of aninterantion ...?+with magnesium with ther the product dissolved with waten? (Grignard regunt} CAS -o MgloH)cl+ cH3--
(a) Compound D undergoes a reaction with hydrogen bromide, HBr to produce 2-bromobutane. D exists as cis-trans isomers and decolourises bromine solution in methylene chloride, CH2CI2. Sebatian D mengalami tindak balas dengan hidrogen bromida, HBr untuk menghasilkan 2-bromobutana. D wujud sebagai isomer cis-trans dan memudarkan larutan bromin dalam metilena klorida, CH2CI2. (i) Draw and name the structure of compound D. Lukis dan namakan struktur sebatian D. (ii) Draw two (2) constitutional isomers of compound D. Lukis dua (2) isomer berjuzuk bagi sebatian D.
mheducation.com/ext/map/index.html?_con=con&external_browser=D0&launchUrl=https%253A%252F%252Fcompass2g.illinois.edu%252Fweb wing i Saved Complete the reactions to show the synthesis of the following compound from (CH,),CHCH,CH,Br. Part 1: Br K OC(CH3)3 view structure Part 2 out of 2 Br2 H,O What reagent is needed where the "?" is located?
(vi) Explain the differing reactivity in the two reactions below: H2/Pt Mn Cal CO 1 At., RT. Cal CO CH2 CH2 4 H2 [(H,C=CH)PtCl2k 1 At., RT. 2 C2H6 +2 Pt +4 HC
Question 15.dox (Protected View) - Microsoft Word (Product Activation Faile References Mailings Review View Home Insert Page Layout Enable Editing Protected View This file originated from an lInternet location and might be unsafe. Click for more details. Question 15 Page: 1 of 1 Words: 2
and , respectIvtry b) +2, 0 a) +3, -1 c) +2, -2 Q14: salenH2 ligand prepared by a) condensation of salicylaldehyde (1 equiv.) and ethylenediamine (1 equiv.) D) condensation of salicylaldehyde (1 equiv.) and ethylenediamine (2 equiv.) C) condensation of salicylaldehyde (2 equiv.) and ethylenediamine (1 equiv.) d) condensation of salicylic acid (2 equiv.) and ethylenediamine (1 equiv.) e) none of them following proced
p-nitroaniline (2max : 375 nm) absorbs at a longer than Phitrobenzene (c) Explain why wavelength (hmax : 260 nm). (ij Write a short note on absorption. spectra complexes of charge transfer
C Metallic Tanta C The Substance C The Substance C The Substance C Which Of The C Get Homewor O 8 https://east.cengagenow.com film/takeAssignment/takeCovalentActivity.do?locator=assignment-take O Other Bookmarks [References) Use the References to access important values if needed for this question. In a study of the rearrangement of cyclopropane to propene at 500 °C (CH2)3 CH3CH=CH2 the concentration of (CH2)3 was followed as a function of time. It was found that a graph of In[(CH2)3] versus time in seconds gave a straight line with a slope of -1.02x10-3 s-1 and a y-intercept of -2.77. Based on this plot, the reaction is Norder in (CH2)3 and the rate constant for the reaction is s-1 zero first Submit Answer Try Another V second item attempts remaining Previnus Next 7:13 PM 5/5/2022 SONY WEB DISPLAY OFF One Touch Web Access Without Booting Up F8 Num Lk Ser Lk Prt Sc Sys Rq Insert Pause Delete Break F4 F5 F6 F7 F9 F10 F11 F12 -Backspace Home
(2) Draw Suve the to products specify 1)BH 3 2) HzOz, H2O, оно of the sterco chemistry 1) Hg (0AC)₂, H₂0 2) Na BH4 H+ 1 H ₂0 H₂, Rancy Ni below, making where applicable. reactions
CHM 121 DIHyJrolysis of a Compound B Crormuls CH6cla) wss Caried ut ly reftuxing coth excess Potassium hydrosede Solution the resulting Solution wss acıdıfied wrth dilute nitrc acid and excess Siluer nitrate added to precipitefe the Chlonde as Siluer Cloloride O.7189 of Siluer Ch loride was Farmed rom 0.80590F B- 9 Calculafe the number Of Chlurine atoms Present in esch molecele OF B Cohich are libersfed loy byloysıs (ung
a) CI Ph3PlI. - PPH3 Rh PPH3 + H2 ? Ph3P CO b) Mn2(CO)10 + HCl c) CH3I CO CO CH4 d) Co2(CO)s + H2 CO e) [Fe(CO),(CH;)]* + CH;CH,Br [기 → ? f) H A +PPH3 PPh3 Ph3P g) EtgPl.pt- + LICH3 + PHCH,Br EtgP