Explain the following periodic trends: (a) melting point of BiF3 (650 °C) >» melting point of PF3 (-150 °C); (b) SnF2 exists, but SiF2 does not.
Q: Why does sodium fluoride have a melting point of 993°C but nitrogen has a melting point of -210°C?
A: Please find your solution below : Melting point of any substance is defined as the temperature at…
Q: VF5 is a liquid that boils at 48°C, whereas VF3 is a solid that melts above 800°C. Explain this…
A: The reason why VF5 is a liquid that boils at 48°C, whereas VF3 is a solid that melts above 800°C has…
Q: Given MnO2, FeCl3, Pt, and Ni, which would you select for decomposing KClO3 to give O2?
A: Catalyst is chemical substance that enhance the rate of chemical reaction but itself remain…
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A: The electrical conductivity represents the ease by which electric current can pass through a…
Q: An element forms an oxide, E2O3, and a fluoride, EF3.(a) Of which two groups might E be a member?(b)…
A: a) The oxidation state of E is +3 as it forms E2O3 and EF3 thus E belongs to 3A or 3B group.
Q: Of the elements Be, C, Cl, Sb, and Cs, which (a) has the lowestelectronegativity, (b) has the…
A: (a)
Q: An element forms an oxide, E₂O₃, and a fluoride, EF₃.(a) Of which two groups might E be a member?(b)…
A: a. (a) When element E form oxide E2O3 then oxidation state of E is +3. When it forms fluoride EF3…
Q: Qu) Are The elements sodium, aluminum, and chlorine are in the same period? And give the right…
A: The given elements sodium, aluminum and chlorine lie in the third period of periodic table. Their…
Q: (ii) Arrange the group VII elements in order of increasing oxidizing strength. Explain the trend.…
A: Hello. Since your question has multiple parts, we will solve the first question for you. If you want…
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A: a. Ag+ , Hg+2 belongs to group - I , where as co+2 belongs to group - IIIB b. All are from group -…
Q: Define the term a substitutional alloy?
A: Alloy is the one which is formed by mixing the metals.
Q: Why alkali metals donot exist as free in nature?
A: Alkali metals are s-block elements or 1A group elements. These metals have only one electron in the…
Q: Diiodine pentaoxide (I₂O₅) was discovered by JosephGay-Lussac in 1813, but its structure was unknown…
A: a) The precursor, oxoacid is iodic acid and the reaction for formation of the oxide is given as…
Q: Consider the following three statements about the reactivityof an alkali metal M with oxygen gas:(i)…
A: Given statements, (i) Based on their positions in the periodic table, the expected product is the…
Q: What is the oxidation number of S in the compound Na,S,O5?
A:
Q: Write a balanced equation for the formation of rubidium bromide through a reaction of a strong acid…
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Q: Does the metallic characteristic of a main-group element increase or decrease as we move down a…
A: The metallic characteristics of a main-group element increases as we move down a family because the…
Q: Why is beryllium carbonate unusually unstable thermally as compared to the other carbonates of this…
A: Beryllium belongs to group 2 in the periodic table. The carbonates of this group are - BeCO3, MgCO3,…
Q: As described in Section 7.7, the alkali metals react withhydrogen to form hydrides and react with…
A: Alkali metals are the elements of the periodic table placed in group-1. They are most…
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Q: (a) One of the alkali metals reacts with oxygen to form a solidwhite substance. When this substance…
A: The periodic table is the representation of the elements in the increasing order of their atomic…
Q: Qu) Are The elements sodium, aluminum, and chlorine are in the same period? And give the right…
A: Given: Q11. Are the elements sodium, aluminium and chlorine are in the same period? a) which has…
Q: How does the basicity of SnO₂ in water compare with thatof CO₂? Explain.
A: The molecules given are SnO2 and CO2.
Q: Treatment of cobalt(II) oxide with oxygen at high temperatures gives Co3O4. Write a balanced…
A: Given that the reaction of cobalt(II) oxide with oxygen gives Co3O4. To find: Balanced chemical…
Q: Give explanations for the large drops in melting point fromC to Si and from Ge to Sn.
A: In the periodic table, the atomic size is decreases across left to right and up to down increases.…
Q: In chemistry, what does it mean when the ratio of the overall Fe in Fe2O3 and Fe3O4 is unity?
A: we are required to find % of Fe in both iron oxide and then compare the % of Fe
Q: Calculate the stoichiometric ratio of Fe3O4 in Fe2O3.
A: Iron (II, III) oxide undergoes oxidation to form Iron (II) oxide.
Q: Which of the following statement(s)is/are correct concerning Group 17(Group VII) elements? They will…
A: The elements present in Group 17 (Group VII) are F2 - Fluorine Cl2 - Chlorine Br2 - Bromine I2 -…
Q: Why is boron limited to a maximum coordination number of four in its compounds?
A: The element Boron belongs to the p-block where the last electron must enter into the p-subshell. The…
Q: . What experimental evidence would allow you to determine whether TiCl4 is an ionic compound or a…
A: Oxidation state of Ti in TiCl4 is as follows: x+(-1×4)=0x=+4
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Q: Would the reaction of beryllium, Be, with oxygen be more or less vigorous than ba?
A:
Q: (a) What is the lanthanide contraction? (b) How does it affectatomic size down a group of transition…
A: Lanthanoid contraction, in chemistry, is the steady decrease in the size of the atoms and ions of…
Q: (b) Is boron a metal or a non-metal? Give reasons for your answer. (c) Why is aluminium a useful…
A: Element can be classified as metal and non metal
Q: How does the maximum oxidation number vary across aperiod in the main groups? Is the pattern in…
A: Main groups include s and p block elements. s block includes group 1 and 2 and p block includes…
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Q: Give the oxidation state of the metal for each of the following oxides of the first transition…
A: Since you have posted a question with multiple sub-parts, we will solve first three subparts for…
Q: Why K2O is diamagnetic in nature?
A: K2O form superoxide ion O2- in which there is an unpaired electron present in anti-bonding orbital.
Q: Alkaline earth metals are involved in two key diagonal rela-tionships in the periodic table. (a)…
A: (a) Two alkaline earth metals; Be and Mg exhibits diagonal relationship. The pair of elements are…
Q: Suppose we introduce the following pointdefects.(a) Mg2+ ions substitute for yttrium ionsin Y2O3;…
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Q: Many lithium salts are hygroscopic (absorb water), whereas the corresponding salts of the other…
A:
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- Give the electron configuration of (a) La; (b) Ce³⁺; (c) Es;(d) U⁴⁺Answer the following: (i) Which neutral molecule would be isoelectronic with CO-? (ii) Of Bi(V) and Sb(V) which may be a stronger oxidising agent and why?The main reason alkali metal dihalides (MX₂) do notformis the high IE₂ of the metal. (a) Why is IE₂ so high for alkalimetals? (b) The IE2for Cs is 2255 kJ/mol, low enough for CsF₂to form exothermically (ΔHf=-125 kJ/mol). This compoundcannot be synthesized, however, because CsF forms with a muchgreater release of heat (ΔHf=-530 kJ/mol). Thus, the break-down of CsF₂ to CsF happens readily. Write the equation for thisbreakdown, and calculate the heat of reaction per mole of CsF.
- Give reasons for the following: (i) N2 is not particularly reactive. (ii) Halogens are strong oxidising agents. (iii) Sulphur hexafluoride is less reactive than sulphur tetrafluroide.Energy is required to remove two electrons from Ca to formCa2+, and energy is required to add two electrons to O toform O2 - . Yet CaO is stable relative to the free elements.Which statement is the best explanation? (a) The latticeenergy of CaO is large enough to overcome these processes.(b) CaO is a covalent compound, and these processes areirrelevant. (c) CaO has a higher molar mass than either Ca orO. (d) The enthalpy of formation of CaO is small. (e) CaO isstable to atmospheric conditions.The melting points of the alkali metals decrease from Li to Cs. In contrast, the melting points of the halogens increase from F2 to I2. (a) Using bonding principles, account for the decrease in the melting points of the alkali metals. (b) Using bonding principles, account for the decrease in the melting points of the halogens. (c) What is the expected trend in the melting points of the compounds LiF, NaCl, KBr, and CsI? Explain this trend using bonding principles. Note: Please briefly explain all the questions listed above. Thank you.
- (a) What is a coordinate covalent bond?(b) Is it involved when FeCl3 dissolves in water? Explain.(c) Is it involved when HCl gas dissolves in water? Explain.(a) What does the term paramagnetism mean? (b) How can onedetermine experimentally whether a substance is paramagnetic?(c) Which of the following ions would you expect to beparamagnetic: O2+ , N22 -, Li2+ , O22 - ? For those ions that areparamagnetic, determine the number of unpaired electrons.(b) Which one of the two compounds you would expect to have a stronger carbon to oxygen bond, CO or Ni(CO),? Explain your choice.
- Give the electron configuration and the number of unpaired electrons for (a) Sc³⁺; (b) Cu²⁺; (c) Fe³⁺; (d) Nb³⁺For each pair, choose the compound with the smaller latticeenergy, and explain your choice: (a) CaS or BaS (b) NaF or MgO3. On the basis of ionic charge and ionic radii given in Table 1, predict crystal structures for the following materials: ( a. CaO (b) MnS (c) KBr (d) CsBr b. Justify your selections. Table 1: Ionic Radii for Several Cations and Anions Ionic Radius (am) Ionic Cation Radius (nm) Anion 0.053 Br 0.196 Ba?+ Ca?+ 0.136 0.181 0.100 F 0.133 Cs* 0.170 0.220 Fe2+ 0.077 0.140 Fe 0.069 0.184 K* 0.138 Mg Mn2* 0.072 0.067 Na* 0.102 Ni+ 0.069 Sit+ 0.040 0.061