Explain your responses to the two (2) parts below very succinctly, that is – in one sentence each only: The reagent NazCr2O7 oxidizes hydroxyl FGs when mixed with hydronium. (a) Do you think these reagents will over-oxidize primary hydroxyls into carboxyls? Why or why not? (b) The secondary hydroxyl and the alkoxy FG below both become oxidized under these conditions. Mechanistically, why do you think this is so? OH Na,Cr,07 CH3 H3C H3C°

Explain your responses to the two (2) parts below very succinctly, that is – in one sentence each only: The reagent NazCr2O7 oxidizes hydroxyl FGs when mixed with hydronium. (a) Do you think these reagents will over-oxidize primary hydroxyls into carboxyls? Why or why not? (b) The secondary hydroxyl and the alkoxy FG below both become oxidized under these conditions. Mechanistically, why do you think this is so? OH Na,Cr,07 CH3 H3C H3C°

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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If anhydrides react like acid chlorides with the nucleophiles, draw the products formed when each of the following nucleophiles reacts with benzoic anhydride [(C6H5CO)2O]: (a) CH3MgBr (2 equiv), then H2O; (b) LiAlH4, then H2O; (c) LiAlH[OC(CH3)3]3, then H2O.
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