FACT: It was revealed that a molecule experiences a configuration inversion during SN2 reactions. 2-Iodooctane that is optically active was reacted with Na131I in acetone. It was found that the reaction's pace was dependent on both [RI] and [I-], however racemization happened at a rate that was twice as rapid as isotopic exchange. Explain these findings in no less than 5 sentences. Illustrate as needed.
FACT: It was revealed that a molecule experiences a configuration inversion during SN2 reactions. 2-Iodooctane that is optically active was reacted with Na131I in acetone. It was found that the reaction's pace was dependent on both [RI] and [I-], however racemization happened at a rate that was twice as rapid as isotopic exchange. Explain these findings in no less than 5 sentences. Illustrate as needed.
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter24: Catalytic Carbon-carbon Bond Formation
Section: Chapter Questions
Problem 24.8P
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FACT: It was revealed that a molecule experiences a configuration inversion during SN2 reactions. 2-Iodooctane that is optically active was reacted with Na131I in acetone. It was found that the reaction's pace was dependent on both [RI] and [I-], however racemization happened at a rate that was twice as rapid as isotopic exchange.
Explain these findings in no less than 5 sentences. Illustrate as needed.
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