For the reaction NH2SO2OH + H2O → NH4HSO4In aqueous solution at 80.35oC, the following constants were observed at the indicated ionic strength μ x103 k (L/mol hr) 5.06 1.07 11.21 1.02 15.85 0.976 22.94 0.886From these data ascertain:a.) the valence of the reacting ions andb.) the rate constant for the primary salt effect. For the reactionNH,SO2OH + H20 → NH4HSO4In aqueous solution at 80.35°C, the following constants were observed at the indicatedionic strengthH x103k (L/mol hr)5.061.0711.211.0215.850.97622.940.886From these data ascertain:a.) the valence of the reacting ions andb.) the rate constant for the primary salt effect.

For the reaction NH2SO2OH + H2O → NH4HSO4 In aqueous solution at 80.35oC, the following constants were observed at the indicated ionic strength μ x103 k (L/mol hr) 5.06 1.07 11.21 1.02 15.85 0.976 22.94 0.886 From these data ascertain: a.) the valence of the reacting ions and b.) the rate constant for the primary salt effect.

For the reaction NH2SO2OH + H2O → NH4HSO4 In aqueous solution at 80.35oC, the following constants were observed at the indicated ionic strength μ x103 k (L/mol hr) 5.06 1.07 11.21 1.02 15.85 0.976 22.94 0.886 From these data ascertain: a.) the valence of the reacting ions and b.) the rate constant for the primary salt effect.

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter5: Introduction To Chemical Equilibrium

Section: Chapter Questions

Problem 5.42E

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Question

For the reaction

NH₂SO₂OH + H₂O → NH₄HSO₄

In aqueous solution at 80.35^oC, the following constants were observed at the indicated ionic strength

μ x10³ k (L/mol hr)

5.06 1.07

11.21 1.02

15.85 0.976

22.94 0.886

From these data ascertain:

a.) the valence of the reacting ions and

b.) the rate constant for the primary salt effect.

For the reaction
NH,SO2OH + H20 → NH4HSO4
In aqueous solution at 80.35°C, the following constants were observed at the indicated
ionic strength
H x103
k (L/mol hr)
5.06
1.07
11.21
1.02
15.85
0.976
22.94
0.886
From these data ascertain:
a.) the valence of the reacting ions and
b.) the rate constant for the primary salt effect.

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