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- Treatment of 1,2-dimethylcyclopentene with OsO4 with NMO produces which of the following? 1 OH CH3 CH3 OH OI O II ||| OIV OV OH CH3 A || OH CH3 OH CH3 H CH3 CH3 ..H for OH CH3 IV CH3 ..H H CH34. What are the products obtained from the following elimination reaction? Indicate the major product. CH;CH2CCH3 H2O CI 5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH;CH,CH,CH,CCH3 Br b) For the major elimination product obtained in 5a), which stereoisomer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.6. What product(s) would you expect to obtain from the following reactions? (a) (c) CH3 NO₂ H₂/Pd KMnO4 H₂O ? ? (b) Br. Br (d) CI. 1. HNO3, H₂SO4 2. Fe, H3O+ OCH 3 ? CH3CH₂CH₂CI AICI3 ?
- 6. Provide the missing products for the following reactions: HO PCC Na₂Cr₂O H₂O° CrO, H₂SO H₂OWhat is or are the expected major product(s) for the reactions below? If applicable, include stereochemistry. Br₂ a) 2-methylbut-2-ene CCI. b) c) a MeOH H₂SO4 1. BH, THF 2. H₂O₂. NaOHDraw a structural formula for the major organic product of the reaction shown below. & CH₂ (oran CH3CH₂O -CuLi 2 ether You do not have to consider stereochemistry. Sn [F ? ChemDoodle H3O +
- Illustrate the structure of the compounds using the following:A. major product between 1,4-dimethylcyclohex-1-ene and BH3, H202, OH-B. major product Of 4-methylpent-2-ene reacted with mCPBA, H20, H+C. major product between 1-methylcyclobut-1-ene and Br2 in dark conditionsD. alkene that formed propanone and carbon dioxide upon reaction with O3, Zn, H2O, H+Please complete the following synthesis of 1,2-dimethylcyclopent-1-ene. Br A Br₂, hv F NBS ? K heat Br B Br₂, DCM G H₂, Pd с HBr, DCM H LDA L Grubb's D HBr, H₂O KMnO4 M CH₂l2, Zn ? E HBr, H₂O₂ J 1. Li, 2. Cul34. Draw the major organic product(s) for the following reactions; (*) must include correct stereochemistry; double-dagger (+) must show two products. HBr (a)* Br HBr Br (b) + (1.00 equiv.) Br Br HBr (c)* HCI (d) 48% wt. HBr 37% wt. HCI HEAT OH [H2SO]/ H20 (g) OCH3 [H2SO,]/A CH,OH (excess) (h) [H,SO,1/H20 OH (i)* [H2SO,] / H,0 OH 13
- a Draw the structure of the intermediate (I) for the reaction below. Hg(O2CCH3)2 NaBH4 Product CH;OH H3C • Use the wedge/hash bond tools to indicate stereochemistry where it exists. If the reaction produces a racemic mixture, just drawv one stereoisomer.6. Provide the product for the following selective reaction: NO₂ HO * = Ch₂ AICI,(a) 2-methyl-2-pentanol Draw the structure of the alkene that was used to prepare the alcohol in highest yield. ? ChemDoodle Which process does this employ? 1. Hg(OAc)2, H₂O; 2. NaBH4 1. BH3; 2. H₂O2, NaOH OsO4, H₂O2 √ [F