Given incomplete reaction is : CH4 + Cl2, hv ------------>  (a). Predict products and write complete chemical equation. (b)  Write a stepwise mechanism for monochlorinated product formation.  Be sure to show all the intermediate structure and all the electron flow using arrows.

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1. Sol :- 

Given incomplete reaction is :

CH4 + Cl2, hv ------------> 

(a). Predict products and write complete chemical equation.

(b)  Write a stepwise mechanism for monochlorinated product formation.  Be sure to show all the intermediate structure and all the electron flow using arrows.

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(a)

The given reaction is the photochlorination of methane, which undergoes free radical substitution mechanism in the presence of Cl2, light (hv) o gives mixture of products that is CH3Cl, CH2Cl2, CHCl3 and CCl4. In this reaction, one H of methane is replaced by Cl atom. 

Therefore, complete reaction is : 

 

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Step 3

(b). 

Complete mechanism of photochlorination reaction is :

Step.1 :- Chain initiation step :-

 

Step.2 :- Chain propagation steps :-

 

Step.3 :- Chain termination step :-

 

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