Explain the mechanism in detail Me.ОНCF3CO2HHOMe H.ОНa. TiCl4, CH2CI2-78 ° to 0 °CCl..b. H2O workupCHOMeMe

The mechanism of the reactions are given as

Answered: H. a. TiCl4, CH2CI2 -78 ° to 0 °C Cl..…

Science

Chemistry

H. a. TiCl4, CH2CI2 -78 ° to 0 °C Cl.. b. H2O workup Me CHO Me

Introductory Chemistry: A Foundation

8th Edition

ISBN:9781285199030

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter13: Gases

Section: Chapter Questions

Problem 137AP

See similar textbooks

Related questions

Q: 20) What is the value for Kc if [CO] = 0.025, [H2]= 0.013 and [CH3OH] = 0.0028 for the following…

A: Given:

Q: Weight of crude acetanilide = 2.2 grams Weight of pure acetanilide = 1.5 grams Melting point of…

A: Weight of crude acetanilide = 2.2 grams Weight of pure acetanilide = 1.5 grams…

Q: 1.16 Ti(a) transforms to Ti(B) at 882°C (1155 K), with a heat of transforma- tion equal to 830…

Q: the Chemical Changes experiment (E3) on copper, which of the steps can be omitted if our goal is…

A: The concentration of the sodium hydroxide titrant is determined with the use of KHP as primary…

Q: In the Chemical Changes experiment (E3) on copper, which of the steps can be omitted if our goal is…

A: Hii there, As there are multiple question posted. we are answering first question. If you need…

Q: он H2SO, NABH4, M `NH2 2 (a) Draw curv oduct.

Q: 235L-5. Like polymers, dendrimers are macromolecules (large molecules). Some dendrimers have been…

A: Dendrimers are large molecules that are formed similar to polymerization reaction. Some of the…

Q: 4. HCHO + KMNO4 +_(4a)_ → _(4b)_+ K2SO4 +| MnO24 + H2O 5. CH3CH2ONA + CH3CH2B1 15) + NaBr. 6.…

A: Balance and complete the reactions.

Q: Give an example of ‘shape-selective catalyst’.

A: Some reactions occur fast in chemistry. Some reactions occur at very slow rate. Catalyst is used in…

Q: A 0.9134-g of KIO3 is dissolved in 500-mL distilled water. A 50.0-mL aliquot portion was run down…

Q: A 0.9056 g sample of KBrO3 (MM=167.0) was dissolved in dilute HCl and treated with an unmeasured…

A: Moles of KBrO3 = 0.9056/167 = 0.00542 Moles of thiosulphate required = 6*0.005432 = 0.0325

Q: LOH H Br This content is prot and 1. NaNH2 (excess) 2. CH31 3. Na, NH3 4. 03 5. DMS 1. PBr3 2. Mg 3.…

Q: 7.

A: Cabonyl carbon is more electrophilic centre than alkene . For addition of nucleophile to alkene , we…

Q: A 0.1017 g sample of KBrO3 (MM=166.1) was dissolved in dilute HCI and treated with an unmeasured…

A: To calculate the concentration of sodium thiosulfate , we would need to calculate moles of iodine…

Q: Which is the principle species in EDTA solution at pH 7? H2Y2- H4Y H3Y- HY3- Y4-

A: According to the graph, the principle species in EDTA at pH 7 is HY3-.

Q: The pK1 for germanic acid, H,GEO3, is 9.0. Account for the increase in pK,1 of germanic acid…

A: It is considered likely that germanium is present in the thermal waters in the form of Germanic…

Q: Describe the selectivity and reactivity of (BuLi.LiO(CH2)2NMe2)

A: There are many mechanisms in organic chemistry such as nucleophilic substitution, nucleophilic…

Q: In extraction, usually we saturate the aqueous layer by salt in order to: Select one O a Precipitate…

A: The answer is option c. which is, dry the organic layer(act as a drying agent).

Q: Determine the fixed carbon content * 98% 86-92% 92-98% Anthracite Meta- anthracite Semi- anthracite…

A: Anthracite :- 92- 98% Meta-anthracite:-greater than 98 % Semi-anthracite :- 86-92% Lignite lass than…

Q: Predict the solubility and explain why: a) CdCO3 b) Na2S c) PbSO4 d) (NH4)3PO4 e) Hg2Cl2

A: The maximum amount of solute that can be dissolved in the definite amount of solvent at a fixed…

Q: 2AgI + Zn → 2Ag+ + 2I- + Zn+2 AgI acts as a/an __________________ Zn acts as…

A: Given: Reaction To find: complete the fill in the blanks Solution: Oxidation is the process in…

Q: Melting point: 98-105 Percent yield: 60% did you successfully make pure product? Explain.

A: A question based on IR spectroscopy, which is to be accomplished.

Q: ----- --.. Type of layer: Agueaus. Species contcined: Sodium benzoare, and Combined No OH (ay)…

A: The type of layer and species is answered in the next step:

Q: Calolate AGQ+ 25°C for the reaGHon of nich AHO= +210KJ; ASO=32 h on

Q: Which of the following materials is Not Soluble ( insoluble ) in water ? a) AgCl c) KCl b)…

A: General solubility guidelines for ionic compounds in water are given below:

Q: the product 17.70 ✕ pi

A: Given that : We have to determine the product of the following : 17.70 ✕ π

Q: Calculate the percent dissociation of trimethylacetic acid (C,H,CO,H) in a 0.45 M aqueous solution…

A: Percent ionization/dissociation mainly used for depicting any acid's/base's strength. When a…

Q: 0.098 M K2Cr2O7 titrant was used for titration of 30 mL of aqueous Ethanol (C2H6O) solution and…

Q: (CH3)2CHCN A) SP. B) sp2 C) sp3 D) none of the

Q: S,0g? (aq) + C20,?(aq) → 2SO,2 (ae) + 2CO2(g) ter reaction with 50.00 mL of 0.05006 M Na2C204, the…

A: Molarity of sodium oxalate = 0.05006 M Volume of sodium oxalate = 50.0 mL

Q: Fill in missing part НО Br H₂ Pd/C H₂ Pd/C H₂ Pd/C EtO- Heat ti# give the arrow pushing mechanism…

A: Given reactions in first image are carried out is catalytic hydrogenation i.e. reaction with…

Q: What is the predominant form of EDTA at > pH 10.0? HY3- H2Y2 H3Y- Y4-

A: At pH greater than 10, all the acidic Hydrogens of the EDTA will lost and remain negatively charged.

Q: |CH,CH,l,Cu-Li THF solvent [+] DIBAL-H, cold THF solvent

A: These two reactions are quite efficient to provide ketone and aldehyde from their corresponding acid…

Q: Solution for 0.105g of the K3[Fe(C2O4)3] (MW= 437.2 g/ mol) were dissolved in sulfuric acid and got…

A: In this question determine amount of oxalate by makin equivalents of oxalate and KMnO4 equal.

Q: A bottle of liduckiime C ciBtaoNz Oz 236g|ma). used as da local artestheAichlontarns s0 mt 0t 1…

A: Given data set: Bottle of lidocaine contains 50 ml of a 4.1% solution. Density = 1 g/ml Molar mass…

Q: Which of the following is NOT a chemical reaction? Select one: O a. Decomposition of the protein…

A: A chemical change in the process in which a new compound is formed which shows completely different…

Q: 205g PBr2 dissolved in 12.5g H2O is considered to be

Q: @ Give the mechanism for the fallowing reachoe. CH CHOH exass jOCH3 + HO

A: Acetals are prepared by treating an aldehyde with excess alcohol. Usually, an acid catalyst is used…

Q: Complete these Heck reactions

A: The Heck reaction is the chemical reaction of an unsaturated halide with an alkene in the presence…

Q: corey-kim oxidation

A: Corey Kim is the process of synthesis of aldehydes or ketones by the reaction of primary or…

Q: What is the conversion of 0.50 ft³ to in³?

A: What is the conversion of 0.50 ft3 to In3 ?

Q: Show Saring Meriels 2.

A: Note: According to our guidelines we are supposed to answer only one question. Kindly repost other…

Q: of Remove water NH catalytic H30* pyrrolidine

A: In this question we have to tell the product of the reaction.

Q: appearance of l2(g)?

Q: ng is not indicated by this reaction? KI, H;PO4 ether, 25° Č

Q: borrmad sunHI SW What's More Activity 1. Strength of IMFA and Physical Properties of Covalent…

A: Since you have asked multiple subparts we will answer the first three subparts for you, for the rest…

Question

100%

Explain the mechanism in detail

H.
ОН
a. TiCl4, CH2CI2
-78 ° to 0 °C
Cl..
b. H2O workup
CHO
Me
Me

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Ph O N O Me 1a. LDA, THF, -35 °C 1b. 2,3-dibromopropene 2a. LIAIH4, THF, -78 ° to 0 °C 2b. NaOH, H₂O workup E 66%
Select the monomer used to create the following polymer. CN xell CN CN CN CI CI F F F
MeO₂C. MeO₂C. OMe -OMe 1. NaH, DMF 2. H₂O* No Heat Ph₂P=CH-Me ÇO₂Me Me H
Determine AGrxn for 2 A(g) + B₂(g) → 2 AB(g) A. -400 kJ B. -250 kJ C. -200 kJ D. -100 kJ E. -50 kJ Compound(state) AG (kJ/mol) A(g) B₂(g) AB(g) 0 -100 -150
b. I' 1. DIBAL-H (1.1 eq) hexane, -78 °C to rt 2. CICH₂CO₂H DEAD, Ph3P 3. LIAIH4, THF B
What is the major organic product of the following reaction? H,0/ heat HO2C. .co.CH .co.H HO,C HO HOC (A) (В) (C) (D)
L 1. O3 2. (CH3),S H,SO4 1. Hg(OAc), THF, H,0 PCI5 A E 2. NaBH4 HO, 180 °C H,SO4 KMNO4, A 120 °C FeCl3 Senyawa B, H30* HI KMNO4, A (CH3),NH K. HNO3, H,SO, H.
CO2ME 144°C COOME Me0OC. then 20°C COOME
A. How CO2 be converted value-added products mediated by ionic liquids such as CO2 hydrogenation, HCOOH, CH4 and other hydrocarbons, HCOOCH3 and can to carbonates etc. B. What are biocompatible ionic liquids and their application in pharmaceutics?
Give the organic product formed. x. d OA. I OB. II O C. III O D. IV heat 11 H H x x xB H ? ||| IV
Choose an expression for the equilibrium constant (Kc) for the following chemical equation: 2K2 O2 (s) + 2CO2(g) = 2K2CO3 (s) + O2 (g) [K2CO3]°[O2] Ο Κ. [K2O2]°[CO2]? [CO2]? O K. [02] [K2O2J°[CO2]? O K. [K2CO3]*[O2] [O2] Ko [CO2]?
Give the missing reactant: CO₂CH3 A | O A. I O B. II O C. III O D. IV + [ ² ] ? || heat 4 CO₂CH3 IV