Quantities such as the isothermal compressibility help us to determine changes in the thermodynamic state functions for "real substances". These quantities can be measured through direct laboratory measurements, or through the use of substance-specific equations of state, such as the van der Waals equation.
Quantities such as the isothermal compressibility help us to determine changes in the thermodynamic state functions for "real substances". These quantities can be measured through direct laboratory measurements, or through the use of substance-specific equations of state, such as the van der Waals equation.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter9: Liquids, Solids, And Materials
Section: Chapter Questions
Problem 45QRT: At the critical point for carbon dioxide, the substance is very far from being an ideal gas. Prove...
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I am pretty sure I have done part a, b, and need a limit for C but I can't see how it reduces to 1/p, also need help on the rest of them thank you.
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I follow your solution until you solve for the partial, when I do it I am left with a 3PVm and -2RT expression on my solution, where did they go? You accounted for them in the full derivative but then when doing the algebra they seem to disappear for no reason. Can you explain "Step 3" (at least on here, probably page 3) better?
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