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- Current Attempt in Progress Which compound is a diastereomer of the structure shown? ОН + III. ОН II || IV O There are no diastereomers. I ОТ хо ОН III ОН ||||... IVBuild a model of methylcyclohexane, and use the model to complete the following Newmanprojections of methylcyclohexane in the chair conformation: a. When the methyl group is in an axial or equatorial (circle one) position, the molecule is inits lowest potential energy conformation. b. Label one Newman projection above anti and the other gauche to describe the relationshipbetween the methyl group and C3 of the ring. c. In general, which is a lower PE conformation, anti or gauche? d. Explain how your answer to b and c provide an explanation for why it is more favorable fora large group to be in an equatorial than an axial position.Which compounds contain stereocentres? I. III. Select one: II, IV a. O b. I, II О с. I, III O d. III, IV ОН II. IV. ОН CI ОН
- Complete the heachion While its mechaniem also KNH Ph3 C Aa. Assign the configuration at each stereo center for each of the following reactants. :Br: :Br: beumue ood o e b. Predict the products of the following reaction. Explain the observed stereochemical outcome using Newman projections and draw a mechanism for the following reaction. NaOEt, EtOH sollemoinoa bes sol elgne Ismborih zesv noliemyolnoo Yarsno jowolst aDaD (b c. Assign the stereochemistry of the product. 6.S) Draw the expected major product (except when I explicitly ask for a minor product) in each box NaOCI CH;CO,H : CH,CN : H20 1) `MgBr OH 2) H20 C10H180 C12H240 C12H240 major stereoisomer minor stereoisomer base C13H9F203 "Fiflunisal" NSAID Drug produced by Merck in 1971 NC. CN heat C10H12N2 enant #1 C1OH12N2 enant #2 show "relative stereochemistry" of the methyl groups in the product for full credit. Two enantiomers are produced, draw one in one box, the other in the other box.
- choice. b. (4 pts) Assign configurations ( R or S ) to all stereocenters in the products. vs. (1 pt) Unlike NaBH4, reductions carried out with DIBAL require quantities equimolarof DIBAL and substrate. Can you explain this difference? MinOR Help wirh part B please, please show working outChoose the best description for the selectivity/specificity of the transformation shown below: O stereospecific regioselective ... neither stereospecific nor regioselective both stereospecific and regioselective Save for Later OH2. Identify the structures of C and D in the following reaction sequence. [1] 03 [2] (CH3)2S C NaOH H₂O D C10H140
- REACTIONS Indicate the reagent(s) needed to carry out the following transformations. (Ctrl) c) CH3-CH2-CH2-OH CH3-CH2-CH2-Br | d) H.2. Complete the following: Stereochemistry and regiochemistry may be important. type a) NaOH (aq) b) neutralize ➤ OMe a) LiAlH4, ether NMe2 f) b) H3O+ type b) a) HS SH ZnCl2, H+ b) Raney Ni g) type formation of thioacetal/desulfurization HO type Hell-Volhard-Zelinsky Reaction h) CO₂Et type Wittig Reaction H H₂N OEt OH DCC, CH2Cl2 Ph type a) NaH, THF CO₂Et d) b) BnBr, THE CO₂Et c) NaOH(aq); HCl(aq); heat type type HO type (COCI)2, cat DMF CH2Cl2 j) CI type a) NHEN b) LiAlH, THE c) H3O+ CO₂Me CO₂MeCan someone please label the H1, H2 etc into its respective regions (ie. aliphatic and aromatic regions)? Thank you!