If 1000 L of gasoline has spilled into the street (MW=117 g/mol, density=0.7 g/mL which is true for octane) then firefighters add a lot of a material that dissolves into it that reduces the vapor pressure (liquid octane doesn’t burn, only the vapors). The firefighters put 500 kg of a material into the gasoline and reduced its vapor pressure from the pure partial pressure of 10.0 kPa down to 8.0 kPa. What is the molecular weight of the material that was added? (hint: use Raoult’s Law, which relates changes in pressure to the mol fractions.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter12: Solutions
Section: Chapter Questions
Problem 12.106QE: In the 1986 Lake Nyos disaster (see the chapter introduction), an estimated 90 billion kilograms of...
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If 1000 L of gasoline has spilled into the street (MW=117 g/mol, density=0.7 g/mL which is true for octane) then firefighters add a lot of a material that dissolves into it that reduces the vapor pressure (liquid octane doesn’t burn, only the vapors). The firefighters put 500 kg of a material into the gasoline and reduced its vapor pressure from the pure partial pressure of 10.0 kPa down to 8.0 kPa. What is the molecular weight of the material that was added? (hint: use Raoult’s Law, which relates changes in pressure to the mol fractions.

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