III. Problem Solving. Provide what is asked for in each item. 1. The complex cis-[PtCl₂(NH3)2], which is commonly known as cisplatin, is a chemotherapy medication for the treatment of various types of cancer. When the two chloride ligands in cisplatin are replaced with a bidentate glycolate ligand (OCH₂CO₂), another anticancer drug is produced and this drug is called nedaplatin. A. What is the correct full name of nedaplatin? B. Write the chemical formula for nedaplatin. C. What are the primary and secondary valence of the central metal in the complex? D. What is the geometry of the complex? Show how the d-orbitals split for this geometry. E. Is the complex paramagnetic? Why? 2. Balance the redox reaction below in (a) acidic and (b) basic environment. +MnO4 (aq) Fe³+ +Mn²+ (aq) MnO4 0.56 3. Consider the Latimer diagram shown below for Mn in strong basic solution. Determine the values for w, x, y, and z. Show your solutions. MnO4²- Fe2+ (aq) 0.27 0.62 → MnO₂³- Z → W MnO₂ (aq) 0.15 -0.05 Mn₂037 y Mn(OH)₂ -1.56 Mn
III. Problem Solving. Provide what is asked for in each item. 1. The complex cis-[PtCl₂(NH3)2], which is commonly known as cisplatin, is a chemotherapy medication for the treatment of various types of cancer. When the two chloride ligands in cisplatin are replaced with a bidentate glycolate ligand (OCH₂CO₂), another anticancer drug is produced and this drug is called nedaplatin. A. What is the correct full name of nedaplatin? B. Write the chemical formula for nedaplatin. C. What are the primary and secondary valence of the central metal in the complex? D. What is the geometry of the complex? Show how the d-orbitals split for this geometry. E. Is the complex paramagnetic? Why? 2. Balance the redox reaction below in (a) acidic and (b) basic environment. +MnO4 (aq) Fe³+ +Mn²+ (aq) MnO4 0.56 3. Consider the Latimer diagram shown below for Mn in strong basic solution. Determine the values for w, x, y, and z. Show your solutions. MnO4²- Fe2+ (aq) 0.27 0.62 → MnO₂³- Z → W MnO₂ (aq) 0.15 -0.05 Mn₂037 y Mn(OH)₂ -1.56 Mn
Chapter21: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 71AE
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Atomic Structure
The basic structure of an atom is defined as the component-level of atomic structure of an atom. Precisely speaking an atom consists of three major subatomic particles which are protons, neutrons, and electrons. Many theories have been stated for explaining the structure of an atom.
Shape of the D Orbital
Shapes of orbitals are an approximate representation of boundaries in space for finding electrons occupied in that respective orbital. D orbitals are known to have a clover leaf shape or dumbbell inside where electrons can be found.
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