In the reactions involving 1-butanol, 2-butanol and 2-methyl-2-propanol with the formula C4H9OH describe what each of the following tests showed about the reactivity of the -OH group and reactions of 1°, 2°, and 3° alcohols. The test with neutral KMnO4 The test with concentrated HCl

In the reactions involving 1-butanol, 2-butanol and 2-methyl-2-propanol with the formula C4H9OH describe what each of the following tests showed about the reactivity of the -OH group and reactions of 1°, 2°, and 3° alcohols. The test with neutral KMnO4 The test with concentrated HCl

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter21: Benzene And The Concept Of Aromaticity

Section: Chapter Questions

Problem 21.39P

See similar textbooks

Related questions

Q: What reaction would be best for preparing 2-isopropoxy pentane in high yield?

Q: Br Mg ether OH 2 H3O+ MgBr O 11 EtO OEt exc TE

Q: Starting with cis-3-hexene, show how to prepare the Meso 3,4-hexanediol diol

A: Meso 3,4-hexanediol needs a syn addition of two hydroxyl groups to cis-3-hexene. This can be done by…

Q: For this question, n-Butanol (CH3CH2CH2CH2OH) and t-butanol ((CH3)3COH) are converted to their…

A: Nucleophilic-Substitution reaction : It is substitution reaction where a neuclephile attack a…

Q: reaction conditions would you use to carry out the following conversions. No 2. of the reaction…

A: The questions are based on the concept of organic reactions. We have to convert the given…

Q: Propose mechanisms to show the interchange of protons between ethanol molecules under(a) acid…

A: The mechanism of the interchange of protons between ethanol molecules under acid catalysis is shown…

Q: An alkene reacts with water with an acid catalyst results into a formation of: A. Aldehyde B.…

A: Please note: As per our company guidelines we are supposed to answer only three parts of one…

Q: The following compounds from the Grignard reaction mixture could be separated by which one of these…

A: In the reaction of grignard reaction in which Biphenyl and triphenyl methanol was the products.…

Q: Write the structure of the principal organic product formed in the reaction of 1-propanol with each…

A: Since we only answer up to 3 sub-parts, we’ll answer the first 3. Please resubmit the question and…

Q: Propose mechanisms to show the interchange of protons between ethanol molecules under base…

A: Catalysis is defined as the phenomenon which increases the rate of chemical reactions. The rate of…

Q: Answer the follow questions below utilizing the reaction provided: 1a. What change, if any, if…

A: In esterification reaction, a carboxylic acid and an alcohol reacts to form an acid.

Q: Apply retrosynthetic analysis to guide the preparation of each of the following compounds from the…

A: While converting from 1 compound to another, organic reagents are used.

Q: 8. Under anhydrous conditions, 4.8 mL of 1-bromo-3,5-dimethylbenzene (dens. 1.36 g/mL) is treated…

A: 8. Given reaction, Moles to mass conversion: Moles = massmolar mass Mass = moles…

Q: . In the synthesis of 1-bromobutane, what is the inorganic by-product left in the reaction flask…

A: Explained as follows

Q: Write the products of the following sequences of reactions. Refer to your reaction roadmap to see…

Q: Which statement correctly describes the expected major product of the reaction sequence shown.…

Q: Pease indicate the compound that best fits in the blank of the separation scheme below. 0000 OH OH…

A: The organic compounds present in the mixture are benzocaine, phenol, biphenyl and benzoic acid.

Q: 3. Consider the following carboxylic acid (propanoic acid) and answer the question that follows:…

A: Since you have posted a question with multiple subparts, we will solve first three subparts for you.…

Q: Give the name of the product between benzyl alcohol and pyridinium chlorochromate.

A: Note : Since you have posted multiple questions, we are entitled to answer the first only. Please…

Q: A chemist wanted to synthesize the anesthetic 2-ethoxy-2-methylpropane. He used ethoxide ion and…

Q: Write the products of the following sequences of reactions. Refer to your reaction roadmap to see…

A: Road map formed by using the given reagents:

Q: starting with 1-bromobutane give a sequence of laboratory reactions which could be used to produce…

A: Here we have to give sequence of synthesis of 1-phenyl-1pentanol from 1-bromobutane-

Q: Consider the following diol: HO, OH What product will be produced by the reaction of this diol with…

A: PCC (pyridinium chloro chromate) is an oxidizing reagent. It is used primarily for the oxidation of…

Q: In a Grignard synthesis of benzoic acid experiment, a student determines that their crude product…

A: Given the crude product has benzoic acid and benzene. Step-1: Add Methyl tert-butyl ether (MTBE)…

Q: Which of the following compounds are suitable solvents for Grignard reactions? 1,4-dioxane

A: 1,4-dioxane compound is suitable for Grignard reaction.

Q: Suggest a synthetic strategy for the synthesis of 6-methyl-3-heptanol from 4-methylpentanenitrile,…

Q: Which of the following compounds would be the most soluble in H0 during extraction purification? A.…

A: ✓It has been found that {\rm{p}}{{\rm{K}}_{\rm{a}}}pKa value of 2- chlorobutanoic acid is lower…

Q: Predict the product for the following reactions. Below each question, write a sentence explaining…

Q: Which of the following extractions would involve a gas being generated? extraction of acetic acid…

A: Introduction to exraction : When a reaction is completed , mostly the solution does not contain the…

Q: 6) If you are given a mixture consisting of following 3 compoünds components by solvent extraction…

A: Given three compounds: Cyclopentylamine (A) is basic in nature. 2,4-cyclopentadiene-1-carboxylic…

Q: Why is potassium hydroxide added to the reaction mixture? To protonate the phenol To deprotonate the…

A: Williamson ether synthesis is reaction in which ether is synthesize from the organohalide and…

Q: Explain the role of the starch iodide test during the oxidation reaction and explain the reagent…

A: The starch-iodine test is a test performed to test the presence of starch or iodine. When starch and…

Q: TRUE OR FALSE 1. Chlorination of benzene occurs even if the reagent AlCl3 is missing. 2. The…

Q: 3. Lucas Test Test Sample 1-butanol Appearance of the Mixture +/- 2-butanol tert-butyl alcohol…

Q: 8. Organometallic reagents, such as organolithium (RLi), Gilman or Organo-cuprates (R2)CuLi) and…

A: LiCH3 is the organolithium compound that releases CH3 as a nucleophile which attacks the carbonyl…

Q: Write reactions of 1-iodo-2-methylpropane with the following reagents: d. CH3NH3 e. NaNO2

Q: Synthesis of 1-bromobutane from 1-butanol (11 mL) – N-butanol (7.4 mL) – Sulfuric acid Give the…

Q: the reaction of the phenol nitration, a mixture of o-nitrophenol and p-nitrophenol is formed. The…

A: We will explain melting point

Q: 2. Is the hydrolysis of benzonitrile to benzoic acid carried out in today's experiment acidic or…

A: As per statement of experiment ( basic hydrolysis of benzonitrile) means getting benzoic acid from…

Q: 2. Alcohols Write the complete step-by-step mechanism for the reaction of 3-methyl-2-pentanol with…

A: When 3- methyl-2-pentanol treated with Sulphuric acid, then dehydration Reaction takes place and…

Q: Show how to convert 1-phenylpropane into the following compound . In addition to this starting…

A: Synthesis is a sequence of two or more reactions designed to obtain a definite end or final product.…

Q: Give an implication or an inference to the following reaction below 1. effervescence where formed…

A: Effervescence occurs when gas escapes from an aqueous solution, thereby causing a foaming in the…

Q: For the following pairs, determine what could be the best solvent to differentiate them based on…

A: Here we have to determine the best solvent that can differentiate between the pair of the following…

Q: Explain in detail how you would separate benozic acid from phenol, using either lithium hydroxide,…

A: Separation of two compounds Separation of two compounds can be done using a separating funnel that…

Q: Questions 1,3 and 5

A: An acid catalyzed dehydration of 2-methyl-2-butanol was performed to produce a mixture of isomeric…

Concept explainers

Designing a Synthesis

Organic synthesis is a branch of chemical synthesis that involves the planned construction of organic compounds/molecules from smaller units that possess functional groups. Friedrich Wöhler was the first scientist who designed the synthesis of an organic compound, urea from inorganic starting materials silver cyanate with ammonium chloride via a simple, one-step synthesis.

Question

In the reactions involving 1-butanol, 2-butanol and 2-methyl-2-propanol with the formula C4H9OH
describe what each of the following tests showed about the reactivity of the -OH group and reactions of 1°,
2°, and 3° alcohols.

The test with neutral KMnO4

The test with concentrated HCl

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 3 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

1. In the reactions involving the three isomeric alcohols with the formula C4H9OH, describewhat each of the following tests showed about reactivity of the -OH group and reactions of 1°,2°, and 3° alcohols.• the test with neutral KMnO4• the test with concentrated HCl2. Predict how the fourth alcohol with the formula C4H10O would react if tested with:• 0.01 M KMnO4• concentrated HCl at room temperatureExtend FurtherUse your observations of the solutions formed in the previous experiments and yourunderstanding of alcohols to complete a table like the one shown below. Research the meltingand boiling points to verify your answers.
Materials • 1-butanol • 2-butanol • 2-methyl-2-propanol • 3 mol/L H2SO4 (aq) • 3 mol/L NaOH • 0.01 mol/L KMNO4 • concentrated (12 mol/L) HCl (aq) for demonstration use only • distilled water • 10 mL graduated cylinders or graduated medicine droppers • test tubes • test-tube rack Procedure Part 1: The comparison of three isomeric alcohols reactions with potassium permanganate 1. Construct an observation table with the following headings. Alcohol Observations at 1 minute Observations at 5 mins 1-Butanol 2-Butanol 2-Methylpropanol
II. Choose one test to differentiate the following pairs of compounds from the given tests. Underline the name of the compound which will yield a positive result. Qualitative Tests: Baeyer's test Ammoniacal silver nitrate test Combustion test Beilstein test Alcoholic silver nitrate test Compounds Cyclohexene Test benzene 1-butyne 2-butyne 2-methylpentane 2-methylpentene 1-chloropentane 2-chloro-2-methylbutane
Write the Ky reactions for pyridine, for sodium 2-mercaptoethanol, and for cyanide. H+ binds to S in sodium 2-mercaptoethanol and to C in cyanide. (Hint: Spectator ions, which do not react in solution, appear on both sides of the reaction and can be removed.) N: HOCH.CHS: Na+ CN Pyridine Sodium 2-mercaptoethanol Cyanide Refer to the Ka values below for their conjugate acids. Which of the three bases shown above is the strongest? NH HOCH.CH.SH HCN Pyridinium ion K. = 6.3 x 10-6 2-Mercaptoethanol K. = 1.9 X 10-10 Hydrogen cyanide K = 6.2 x 10-10
Which of the following statements is true10. As the alkyl chain increases in molecular weight among primary alcohol, the solubility in water increases. 11. An ethoxide ion exhibits greater proton-accepting property compared to an ethyloxonium ion. 12. Phenol is more acidic than cyclohexyl alcohol due to the electron-donating ability of phenolic oxygen.
Which tests show can be used to show that a phenol is present? Select one or more: lodine test Lucas test Iron(III) chloride test Acidity test
TRUE OR FALSE 15.In Fehling’s test, the theoretical product after an aldehyde is mixed with Fehling’s solution is alcohol. 16.Iodoform, which has a molecular formula of CH3I, is indicative that ketomethyl group is prresent. 17.Based on the physical property, hydroquinone has a lower boiling point compared to catechol. 18.When FeCl3 is used in visualizing aspirin in tin layer chromatography, the resulting spot is in red color.
Thiols or thiol (-SH) group is a better base than hydroxide (-OH) group in elimination reactions.
Write out the steps needed to separate hydrocarbon A and carboxylicacid B by using an extraction procedure.
What can be concluded about the chemical properties of alcohols and phenol using the following qualitative tests: Iodoform Test Lucas Test Chromic Acid Test Iron (III) chloride Test
How could you separate a mixture of ethanol, 1-pentanol and 1-octanol. Discuss the steps in your procedure.
2. What kind of results do you expect to see when the following compounds are mixed together with the given test solution? Indicate positive or negative in the table below. (a) O with 2,4-dinitrophenylhydrazine (b) with Benedict's reagent (c) with iodoform reagent (d) with Tollen's reagent H JH H CH3