(k) (m) -C=N (1) CH,MgI (2) H3O+ CH3 PhCH,—CH–CH,—C–NH, 1. excess CH3MgBr 2. H₂O 1. excess LiAID4 2. H₂0

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter20: Carboxylic Acids And Nitriles
Section20.2: Structure And Properties Of Carboxylic Acids
Problem 4P: The Ka for dichloroacetic acid is 3.32 Ă— 10-2. Approximately what percentage of the acid is...
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Can you propose a mechanism for the problems i,k , and m? I've also included the answers for the products that the reactions make, I'm just confused with the mechanisms.

(i)
(k)
(m)
-C=N
(1) CH,MgI
(2) H3O+
CH3
PhCH,—CH–CH,—C–NH,
1. excess
CH3MgBr
2. H₂0
1. excess
LiAlD4
2. H₂O
Transcribed Image Text:(i) (k) (m) -C=N (1) CH,MgI (2) H3O+ CH3 PhCH,—CH–CH,—C–NH, 1. excess CH3MgBr 2. H₂0 1. excess LiAlD4 2. H₂O
(f)
C.
a &
OCH 3
H
OH
(k) CH3 D
PhCH,CH,CH,CNH,
I
D
LIAID4 reduces the C=0;
H₂O replaces the H on N.
(h) HỌPh
(1)
z
OH
transesterification
OH
Ph
OH
584
(i)
(m) H3C CH3
HO
HO
-C-CH3
(n)
D D
HOX
HO
HO
NH₂
Na+
Transcribed Image Text:(f) C. a & OCH 3 H OH (k) CH3 D PhCH,CH,CH,CNH, I D LIAID4 reduces the C=0; H₂O replaces the H on N. (h) HỌPh (1) z OH transesterification OH Ph OH 584 (i) (m) H3C CH3 HO HO -C-CH3 (n) D D HOX HO HO NH₂ Na+
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