KHP is an ionic compound composed of a potassium cation K+ and a hydrogen phthalate anion HP– . HP– is a weak acid and upon dissolving in water, can lower the pH of the solution. (a) Suggest the chemical reaction(s) when a solid sample of KHP is dissolved in water, writing out the chemical equations for them. (b) Sketch the structure of KHP from above and circle the hydrogen atom that is responsible for its acidity. (c) Calculate the pH of a solution made of 0.50 g of KHP and 50 mL of water. KHP has a molar mass of 204.2 g mol and at 25 °C has a pKa of 5.4.

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Group 15 elements

The elements of group 15 are phosphorus, nitrogen, bismuth antimony, and arsenic. The most abundant element which is present in the air is nitrogen and the percentage of nitrogen present in the air is 78%. In the free state, the elemental nitrogen is present as diatomic gas (N2). In the organic matter obtained from plants and animals, phosphorus is the dominant element present. In nucleic acids, phosphate groups are present. Phosphates are also found in teeth and bones. The other elements arsenic, bismuth, and antimony are found as sulfides. Arsenopyrite, bismuth glance, and stibnite are examples of sulfides of arsenic, bismuth, and antimony respectively.