most of the additions of bromine to double bonds gave entirely antistereochemistry. Explain why the addition to phenanthrene gives a mixture of synand anti stereochemistry
most of the additions of bromine to double bonds gave entirely antistereochemistry. Explain why the addition to phenanthrene gives a mixture of synand anti stereochemistry
Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution
Section16.SE: Something Extra
Problem 34MP: Using resonance structures of the intermediates, explain why bromination of biphenyl occurs at ortho...
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most of the additions of bromine to double bonds gave entirely anti
stereochemistry. Explain why the addition to phenanthrene gives a mixture of syn
and anti stereochemistry
Expert Solution
Step 1
Additions of bromine to double bonds:
In most cases, the additions of bromine to double bonds gave entirely anti stereochemistry, due to the formation of bromonium ion as an intermediate. The nucleophilic attack from the opposite side results in anti-stereochemistry.
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