Answered: polymerization of the protected…

polymerization of the protected dithiocatechol monomer. Draw the product for the following reactions. Assume termination occurs by disproportionation. AIBN THF, 60 "C, 24 h S-

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter29: Organic Polymer Chemistry

Section: Chapter Questions

Problem 29.27P

See similar textbooks

Related questions

Q: Which reaction is slowest? inin reaction coordinate reaction coordinate reaction coordinate A B А) A...

Q: 0.333 g of a hydrocarbon (CxHy) was analyzed by combustion analysis and 1.009 g of CO2 (MM = 44.01 g...

A: Mole concept: The number of molecules or atoms present in the one mole of the substance is equal to ...

Q: At 298 K, the enthalpy of denaturation of hen egg white lysozyme is 217.6 kJ/mol. The change in heat...

Q: An isotope of element A contains the same number of neutrons as are found in an atom of $1V. The iso...

A: Atomic number of the elements indicates the number of protons present in the particular atom. Mass ...

Q: WHAT IS THE RIS CONFIUURATION RELAFION SHIP? Br OH VS HO Br.

Q: How many calories are needed to raise 10 g of ice at -5 °C to steam at 100 °C ....

Q: 3. Diethyl ether (molar mass 74.12 g/mol) boils at 34.6 °C and water (molar mass 18.02 g/mol) boils ...

A: The temperature at which vapour pressure of a liquid is equal to the atmospheric pressure is called ...

Q: Determine how many chiral centers are there?

A: Chiral molecules in which carbon atom with four nonidentical substituents. Such a carbon atom is cal...

Q: The Bayer process is the formation of aluminum hydroxide from metallic aluminum and sodium hydroxide...

A: The Bayer process , Al(s)+ 3NaOH(aq) -->Al(OH)3(s) + 3Na(aq)

Q: name 7-isopropylmethyl-4-nonyne 7,8-dimethyl-4-nonyne 2-isopropyl-4-nonyne 1,2-dimethyl-5-nonyne

A: Here we have to name the given compound according to IUPAC nomenclature rules.

Q: a) Draw the structural formula of aspartic acid. b) Circle the atoms in your formula which would ...

A: The mentioned compound in the question is a well example of amino acid having an acidic moiety attac...

Q: 1 Balance the following equations: a) C(s) bFe(s) + c) P(s) d) C,H,(g)+ --> CO(g) 2 FeCl,(s) P,O,(s)...

A: Given reactions are : a). C (s) + O2 (g) -------> CO (g) b). Fe (s) + Cl2 (g) ---------> FeCl...

Q: pH

Q: Draw a reasonable mechanism for this reaction. Interactive 3D display mode Ph Ph-P=CH, CH2 Ph

Q: Hypothetical reaction A2 A The In Kp = -33.47 at 2000K while deltaH0 = 205200 +4.94T - 0.888*10-3...

A: Given, Hypothetical reaction : A2⇋ A ln Kp=-33.47 ∆H°=205200+4.94T-0.888×10-3T2

Q: (c) The alkyl halide cis-1-bromo-4-methycyclohexane (A) undergoes a substitution reaction when treat...

A: We are given three part of an organic problem based on stereochemistry of organic molecules.

Q: 1. What is the volume occupied by an aluminum sheet with a mass of 5.28 g? Density of Al = 2.7 g/cm³...

A: Note - Since you have asked multiple question, we will solve the first question for you. If you wan...

Q: Will there be a color change if KMnO4 is added to (a) Cyclohexane , (b) Cyclohexene, (c) Toluene ? ...

A: Given data Cyclohexane + KMnO4 ——-> Cyclohexene + KMnO4 ——-> Toluene + KMnO4. ——-&g...

Q: On dissolving 7.258 gm of HCN (Ka=7.2x10 1) in water, the solution become 100 ml so the degree of io...

A: HCN is a Weak acid the degree of dissociation of a weak acid or base or an electrolyte was explained...

Q: Part A Na Na + Express your answer as a particle or a chemical formula. ΑΣφ ? OA chemical reaction d...

Q: The acid constants of the polyprotic acid НЗASO4 are К_a1 %3D 5х10 ^-3, К_а2 - 8х10^-8, К_а3 %3D 6х1...

Q: products

Q: In the synthesis of a protected monosaccharide, you are treating the TLC plate with 5% of sulfuric a...

Q: 1. Calculate the grams of K2SO4 required to make 350.0 mL of a 0.57 M K2SO4 solution. 2. How many L ...

A: Note: As per our company guideline we can answer only three subparts. Kindly repost the question men...

Q: Which atoms could have the valence electron configuration shown below? a. N3- b. O²- С. Ar d. CI'- e...

Q: Choose the mechanism that forms the main product of the following reaction. Er ONa CH3CHOH calor

Q: Brett is performing an experiment where he produces Ammonia gas from Nitrogen gas and Hydrogen gas. ...

Q: At constant Tand n, the pressure of a gas can be doubled by: decreasing volume to half O doubling vo...

A: At constant T and n ,the pressure of a gas can be doubled by given answer as below.

Q: Compute the molecular formula of the following a. 19.1% Sn and 80.9% I b. 25.9% Fe 74.1 Br

A: Given, a. 19.1% Sn and 80.9% I b. 25.9% Fe 74.1 Br Compute the molecular formula of the following =...

Q: Cyanogen has the formula C2N2. Propose a bonding scheme that gives each atom the correct number of c...

A: The determination of the hybridization of central carbon atom in the given molecule is quite necessa...

Q: Calculate the molar mass of the following compounds. Please answer 1-2 and show your work. 1. C8H10...

Q: Physical chemistry question: Calculate the separation between the two lowest energy levels for an N...

A: Given that : Length of the container (l) = 2 cm = 0.02 m Energy of molecule at 300 K =12kT Planck's ...

Q: A compound of bromine and fluorine is used to make UF6, which is an important chemical in processing...

A: Mass percentage of bromine is 58.37% Moles of bromine and flourine and emperical formula is calculat...

Q: What volume does 38.5 grams of HArF occupy? A V-M- a. 164 Liters b. 862 Liters C. 14.4 Liters d. 4.5...

Q: (a) What is the most stable oxidation state of nickel in acidic solution? (b) Show a balanced equati...

A: The frost diagrams show the stability of the oxidation of state of an element relative to other oxid...

Q: 1. OMe Meo Meo в Which of the above compounds absorbs the highest energy photons? Which of the above...

Q: It binds the different components in a ceramic mixture. O coke O alum O feldspar O filler

A: The correct option is:

Q: A car bumper is plated with chromium using chromium (III) ions in solution. If a current of 54A flow...

Q: The breaking buffer that we use this week contains 10mM Tris, pH 8.0, 150mM NaCl. The elution buffer...

Q: Ph Ph

A: The coreactant for the given transformation is aldehyde and reaction proceeds in basic medium.

Q: 2. Write the formulas for the following compounds: a) tribromine octaoxide b) tetraiodine nonaoxide ...

A: Note : As per our company guidelines we are supposed to answer only first 3 sub-parts. Kindly repost...

Q: 4. Propose a structure(s) for the product(s) of the following reactions. O2N. HO NaH H2SO4, HNO3 H2S...

A: Note - Since you have posted a question with multiple sub-parts, we will solve first three sub-parts...

Q: In a salt/water solution, where water is in the greater amount, what is the solvent v Choose... wate...

Q: Ben is pumping up his bike tires using a bike pump. He pushes down on the pump, and the volume goes ...

Q: 1. Draw 2D chemical representations of atactic, syndiotactic, and isotactic polystyrene. 2. Calculat...

A: First three question answered below:

Q: .The specific heat of ethyl alcohol is 2.45J / g°C and that of silver is 0.235J/g°c. Therefore, 10.0...

Q: 23. The following data were measured for the reaction BF3(g) + NH3(g) ---> F3BNH3(g) Experiment [BF...

A: Given, BF3(g) + NH3(g) ---> F3BNH3(g) Overall order of reaction = ? Experiment [BF3] (M) [NH3]...

Q: Suppose the pressure of 5 mol of nitrogen initially at 25 °C and 10 bar is suddenly dropped to 1 bar...

A: The solution is given below -

Q: Add the remaining atoms to compounds A,B,C PPH3 -> NaHMDS . H, 11

Q: The reaction of iodine atoms in the gas phase to form molecular iodine is second order with respect ...

A: Given, Initial concentration, [A]0 = 0.42 M Rate constant, k = 7.0 x 10+9 Ms

Concept explainers

Types of Polymers on the basis of Method of Preparation

Question

polymerization of the protected dithiocatechol monomer. Draw the product for the
following reactions. Assume termination occurs by disproportionation.
AIBN
THF, B0 C, 24 h

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step 3

VIEW

Step by step

Solved in 3 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Types of Polymers on the Basis of Method of Preparation

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Styrene derivatives such as A can be polymerized by way of cationic rather than radical intermediates. Cationic polymerization is an example of electrophilic addition to an alkene involving carbocations. a.) Draw a short segment of the polymer formed by the polymerization ofA.b.) Why does A react faster than styrene (C6H5CH=CH2) in a cationicpolymerization?
3. Which of the following could be polymerized by cationic or anionic chain polymerization(or both or neither)? CN Ph он co,CH, Do
What polymer is formed in each of the following reactions? Draw each polymer in polymer notation.n →> Catalyst Part B CH₂ Catalyst n CH H* 12D EXP. CONT. Marvin JS by ChemAxon A # H с N S CI Br - PF
Draw the starting structure that would lead to this polymer under radical cond
1. which cannot be obtained by radical polymerization of its vinyl monomer Poly(ethylene) obtained by polymerization of ethylene monomer Poly(propylene) obtained by polymerization of propylene monomer Poly(vinyl chloride) obtained by polymerization of vinyl chloride monomer Poly(acrylonitrile) obtained by polymerization of acrylonitrile monomer
Which monomer was used to make the polymer shown? О B OH B) OH "JON" орон х D) Zom OH НО A) C)
Draw a structural formula of the polymer resulting from base-catalyzed polymerization of each compound. Would you expect the polymers to be optically active? (S)-(+)-lactide is the dilactone formed from two molecules of (S)-(+)-lactic acid.
What products are formed by ring-opening metathesis polymerization ofeach alkene?
As we will learn in Chapter 28, styrene derivatives such as A can be polymerized by way of cationic rather than radical intermediates. Cationic polymerization is an example of electrophilic addition to an alkene involving carbocations.a.Draw a short segment of the polymer formed by the polymerization of A. b.Why does A react faster than styrene (C6H5CH=CH2) in a cationic polymerization?
Question 4. Methylvinyl ketone (MVK) can undergo a polymerization reaction in the presence of AIBN initiator to produce a poly(methylvinyl ketone) polymer according to the scheme below. NEC H3C CH3 `N=N₂ CH3 CEN CH3 azobisisobutyronitrile (AIBN) CH3 methylvinyl ketone (MVK) heat CH3 H3C NEC n poly(methylvinyl ketone) a) Provide the mechanism for heat-induced decomposition of the AIBN initiator to produce a reactive radical species. CH3 NEC H3C `N = N heat CH3 CEN CH3 10 0-0 b) Provide a mechanism for the initiation step in the MVK polymerization reaction: c) Show the mechanism for the propagation step to form an MVK oligomer with n = 3: branched sidare tass xy ha et
Draw the organic product that is expected to form when the following compound is oxidized under biological conditions. oxidation reduction 0 SH • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. If no reaction occurs, draw the organic starting material. / BO O-Sn [F ChemDoodle Previous M
A3 Anionic polymerization of styrene is generally known to produce polymers with a narrow molecular weight distribution. Explain the reason for this.