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- PQ-4. Predict the major product(s). (A) I Br (B) II Nal acetone Q I (C) III II (D) I and II IIIH3C₂ Br H₂O a. Enantiopure (1R, 3R)-3-Methylcyclohexanol b. Achiral 1-Methylcyclohexanol C. Racemic mixture (1R, 3R)- and (1S, 3S)-3-Methylcyclohexanol d. Diastereomeric mixture of (1R, 3R)- and (1S, 3R)-3-MethycyclohexanolDtermine the reagents that can accomplish the rxn CH2OH (1) Reagent ? (2) Reagent ? C9H1202 (4) Reagent ? (3) H+ a. (1) SOC12 (2) 1-propanol; (4) PCC/pyridine b. (1) NaH, (2) acetone, (4) NABH4 c. (1) NaH, (2) epoxide (4) PCC/pyridine d. (1) Jones reagent, (2) NaH, (4) epoxide
- Q. Identify the products (from 1 to 10) in the following scheme: CI HNO3 1 2 AICI3 H,SO4 Zn(Hg) HCI KMNO4 (hot, concd.) 4 3 Br2 |hv (CH3),CO¯ K* Mg, ether Br2 5 C„H14B12 CH;COCH3 NaOCH3 PHCO3H Fused KOH, 200°C 10 8 Alcohol (3º) An Ether Epoxide derivative 2 5 6 8 9 1012. In the hydrogenation reaction shown, which of the alkenes below would yield the observed products? H₂, Pd/C alkene + one diastereomer || III IV (A) I and II (B) II and III (C) IV and III (D) II and IV (E) I and III3. Predict the product(s) of the following reactions: CH3 CH3CHCH2CH2CO2CH3 2. Hg0* (a) CO2CH2CH3 (b) 1. DIBAH 1. CH3CH2MgBr 2. H30" (c) .COCI CH NH2, ? (d) CO2H CH,OH, ? H2SO4 но CH,CO,COCH,, ? Рyridine (e) CH3 (1) 1. LIAIHA 2. H30 H2C=CHCHCH2CO2CH3 (g) .CONH2 (h) CO2H SOCI2 1. LIAIH, 2. Нао Br CH3 e2016 Cenag Leming
- PQ-6. What is the rate determining step of this reaction? CH₂CH3 (A) HOTS H3C (C) NC CH₂CH3 HOTS H3C CH₂CH3 NaCN Hi H3C (S)-isomer (B) OTS acetone Hi H₂C (D) NC CH₂CH3 CO-H Ts CH₂CH3 ∙H H H₂C CO CN H H3C CH₂CH₂ (R)-isomerThe appropriate product of the following reaction is: H3C- (a) (b) H3C H3C CH3 H3CO CH3 CH3 L S ******** H3CO S 1. Br₂, CH3OH 2. NaSCH 3, DMSO R CH3 SCH3 CH3 S CH3 SCH3 +R, S + R, R (c) (d) H3C. H3C H3CS CH3 ******** H3CS S S R CH3 OCH3 CH3 S CH3 OCH3 +R, S +R, Rch Complete the following reactions by providing the missing products and reagents A-G. i) ii) iii) OH H₂PO4 heat Attach File O C E 2 0 N m-CPBA 1. LDA 2. HBr Pravics Local Cilac Br A ♫ D F 99+ a 1. Mg 2. O 3. H₂O+ B G N
- 4. For the following reactions tell which should have kH/kD values greater than 1.5 for isotopic substitution at the starred hydrogens: (a) -CH=C=0₁ HNEI, CI (b) (c) CH₂ H₂ CH₂ CH NO₂ C CI Et N OH (CH₂ CH CH – CH₂CH₂ OSO₂Ar fo H,C NO EICH NIFT CH₂ + H₂O (CH)!=CH-CH,CH, + ArSO,Hpt pt pt 1 pt C|Chec C Chee C I need 8 https://east.cengagenow.com/ilrn/takeAssignment/take CovalentActivity.do?locator-assignment-take b Answe F3 • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. [References] Draw the structure of the one tertiary (30) alcohol with the molecular formula C5H120. Submit Answer F4 90-85 4+ F5 ¤- CHA 95 IF6 C Draw *+ a O. IF F7 C/C MOTION EYE C Draw F8 SONY Draw F9 C Home WEB k ak DISPLAY F10 F11 C-Draw C One Touch Web Access Withcapp.101edu.co oudy @ 2 X V * UL Week 7: Panopto ||| 3 D E PII $ 4 R Rank these alkyl halides in order of increasing reactivity in an SN2 reaction. F 4x X UL LTU 7-1A F4 HHH % 5 T G 4, CI F5 A 6 4) Y X Question 16 of 24 F6 C|Chegg.com & 7 U F7 ★ A) III < | < || 8 B) || < | < ||| C) ||| < || < | D) || < ||| < | E) | < ||| < || PrtScn 1 FB X + Home ( 9 F9 O ) End 0 D 67 ENG F10 P PgUp Tp S ( D [ * O 6:15 PM 10/18/2022 PgDn + F12 0 SL 3