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- Q2. Provide the reagents O OMe OMe CO₂Me CO₂MeBriefly, but clearly, explain why the –OH hydrogen in acetic acid (CH3CO2H) is more acidic than in ethanol (C2H5OH).Citronellol ((3R)-3,7-dimethyloct-6-en-1-ol, C10H20O) is an organic fragrance found in the oil extracted from lemon grass. a) Name the two functional groups present in the molecule. b) When a few drops of bromine dissolved in hexane is added to a sample of citronellol the brown colour of the bromine rapidly disappears. i. What type of chemical reaction has occurred? ii. Draw the structure of the product formed. iii. Name the product. c) The product formed when citronellol is heated with a mixture of potassium dichromate and sulfuric acid gives a yellow/orange precipitate when shaken with Brady’s reagent (2,4-dinitrophenylhydrazine). It also shows a positive result with Fehling’s solution. i. What type of chemical reaction has occurred ? ii. What type of functional group is present in the product? d) Explain the type of stereoisomerism which may occur in citronellol.
- q D eq eq M req M Preq 0 Match each structural formula on the left to a general functional group classification on the right. CH₂CH₂CH₂CNHCH₂- CH3CH₂CH₂C-OH 0 CH₂CH₂CHCOCH3 CH₂CH3 consomsphẩm CH3 anonpudolg COCCHCH₂CH₂ [Review Topics] CH₂CH₂ CH₂CH3 carboxylic acid ester Clear All anhydride amide [References] none of the above Previous Nex SaveA Q2 Provide products. Br₂ AgNO3 H₂0| CH2C6H5 CH3 + BH3 + H2O2/OH + CrO3, pyridine → A A + CH3-Li + H*/H2O → B
- A chemist synthesized compound X as a racemic mixture. When the ketone group in X was enzymatically reduced to the corresponding alcohol, a 100% yield was obtained of the product shown below. Choose the statement that best describes this result. ОН enzyme C;H1 `OCH,CH; pH 4.0 C3H1 `OCH,CH3 ОН ÕH X (racemic) (100% yield) One enantiomer of compound X reacts quickly with the enzyme. The other enantiomer of compound X is unreactive, but rapidly equilibrates with the reactive enantiomer under the reaction conditions. Since compound X was racemic, it makes sense that only a single product was obtained. O The product is a meso compound, so either enantiomer of compound X gives the same product. One enantiomer of compound X reacts quickly with the enzyme, while the other enantiomer of compound X remains unchanged.Prectice q#7 Draw the "hexagon" line structure of the following (be sure to indicate stereochemistry). -Br OHPhCO₂H + OCH3 O benzene O PHOCH3 O PhCO2 O PhCO2CH3 X?