Question 19 Which of the following alkenes is most likely to undergo rearrangement upon acid-catalyzec hydration (treatment with aqueous H2SO4)? 2 а. 1 b. 2 С. 3 d. 4 a O b O c Oc
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- 9. Draw the constitutional isomer formed when the following alkenes are treated with each set of reagents: [1] H20, H2SO4; or [2] BH3 followed by H2O2, "OH. A io onutouTC.rvinmmoo ewo ebyoleen.g er besibhoyn motis M doso al waH s b. a. Seblaar molsHsno isq onol nose 2eob isticho to eqyt ewni.d Cnistnoo ennug 29ob anodogle yoam woH.o O bns 18 to alnemala erlT nertw bemot witam-S ae doue anexie leohtemmyeni.Which one of the following molecules can react as electrophile in reactions with alkenes? CH3OH NaCI HCI KCN NaCI O HCI O KCN O CH3OH4. What are the products obtained from the following elimination reaction? Indicate the major product. CH3 CH,CH,ČCH, H2O 5. a) Determine the major product that is formed when the alkyl halide reacts with a hydroxide ion in an elimination reaction. CH;CH,CH,CH,CCH, Br b) For the major elimination product obtained in 5a), which stereoisomer (cis or trans) is obtained in greater yield? Draw the two isomers and provide the names of the compounds.
- Which of the following reactions of alkenes is one-step reaction? O a. Bromination (treatment with Br2 in CHCI3) b. Hydrogenation (treatment with H2/Pt) O c. Acid-catalyzed hydration (treatment with aqueous H2SO4) d. Treatment with m- chloroperoxybenzoic acid followed reaction with aqueous acidic solutionWhen alkyne A is treated with NaNH2 followed by CH3I, a product havingmolecular formula C6H10O is formed, but it is not compound B. What isthe structure of the product, and why is it formed?Consider the following mechanism of reaction: CH3 CH, CH3 CH;C CH, + H-CI CH;CCH, + C: → CH;CCH, tert-butyl cation CI tert-butyl chloride In this reaction: The alkene and the carbocation intermediate are both nucleophilic HCl and CI" are both nucleophilic The alkene and HCI are both electrophilic The carbocation and CI" are both electrophilic The alkene and CI" are both nucleophilic AMeving to another question will save this response
- C15T03Q2537 Give the major product of the following reaction. - ? H30* NO, heat -HO- O,N NO, There is no reaction under these conditions, or the correct product is not listed here. OH HO-Draw the organic product that is expected to form when the following compound is oxidized under biological conditions. oxidation reduction 0 SH • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. If no reaction occurs, draw the organic starting material. / BO O-Sn [F ChemDoodle Previous MWhich of the following reaction conditions would result in Markovnikov addition to an alkene? O[1] BH3; [2] H₂O2/HO™ Cl2 HBr, ROOR CH3OH, H₂SO4
- Melamine, used as a fire retardant and a component of the writing surface of white boards, can be prepared from s-trichlorotriazine through a series of SNAr reactions with ammonia. The first substitution takes place rapidly at room temperature. The second substitution takes place near 100 °C, and the third substitution requires even higher temperature and pressure. Provide an explanation fatr this reactivity.Questão 10A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis resulted in CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. What is the reasonable structure for this hydrocarbon? Hexadec-6,10-dino undec-1,5-dino Hept-1,5-dino hex-1,5-dino nahThe following Wittig reactions may produce a mixture of alkene stereoisomers. Write the products for each of the reactions and indicate the stereoisomers if any. || Ph,P CH3 + ? (1) LOME (2) R N. Ph,P=CH,R' Me