Solid Agl and B-alumina (NaAl11017) are both good conductors at elevated temperatures. Pure Zro2 is an insulator but a solid solution ZrO2 (10% CaO) is a good conductor at high temperature.
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- The lead(IV) oxide used in car batteries is prepared by coat-ing the electrode plate with PbO and then oxidizing it to leaddioxide (PbO₂). Despite its name, PbO₂ has a nonstoichiometricratio of lead to oxygen of about 1/1.98. In fact, the holes in the PbO₂ crystal structure due to missing O atoms are responsiblefor the oxide’s conductivity. (a) What is the mole % of O miss-ing from the PbO₂ structure? (b) What is the molar mass of the nonstoichiometric compound?(а) Give an example of zone refining of metals. (b) What is the role of cryolite in the metallurgy of aluminium?(g) Differentiate between hypereutectoid and hypoeutectoid alloys
- Give reasons for the following: (i) Alumina is dissolved in cryolite for electrolysis instead of being electrolysed directly. (ii) Zinc oxide can be reduced to the metal by heating with carbon but not Cr2O3. (iii) Extraction of copper directly from sulphide ores is less favourable than that from its oxide ore through reduction.An impure sample of Na3PO3 weighing 0.1392 g was dissolved in 25 mL of water. A solution containing 50 mL of 3% w/v mercury(II) chloride, 20 mL of 10% w/v sodium acetate, and 5 mL of glacial acetic acid was then prepared. The solution containing the phosphite was added dropwise to the second solution, oxidizing PO3^3– to PO4^3– and precipitating Hg2Cl2. After digesting, filtering, and rinsing, the precipitated Hg2Cl2 was found to weigh 0.4320 g. Report the purity of the original sample as %w/w Na3PO3. Moles Na3PO3 = moles Hg2Cl2(1) A metal that gets covered with a protective film of its oxide (Al, Cu, Ag)(2) A metal which burns in air with golden flame (Zn, K, Na)(3) A metal which can displace hydrogen from boiling water as well as steam (K, Zn, Fe)
- 1. In an experiment, what volume of O2(g) at 0oC and 760 mmHg is produced when 5A of current is passed through a dilute aqueous solution of KCl for 5 minutes?Is it possible to use mesoporous silica nanoparticles (nano carriers)as support of catalysts or bio catalysis for the remediation of pesticides/herbicides applied to soil environment? ThanksRadii were reported as follows: Ti4+ = 60 pm; O2‒ = 140 pm. Based on this, tell as much as youcan about the expected structure of TiO2 – provide the hole type for the cation, the cell lattice,and the coordination numbers for both cation and anion.
- Si is doped with 2x1017 boron (B) atoms/cm³ and 6x1017 phosphorous (P) atoms/cm³. (a) Is this n-type or p-type and why? (b) What are the electron and hole concentrations at 300K? (use ni = 1010 cm³). (c) Calculate resistivity of Si is doped with donor density of Np = 2x1015 (use n¡ = 10!º cm³) and NA = 0 (use n¡ = 1010 ; µn = 1320 cm²/Vs, µp = 460 cm²/Vs) cm (d) In a Germanium semiconductor at T= 250 K (n¡ = 1x1012 cm³), it is found that po = 4no and that Nd = 0. Determine po, no, and Na. (e) Calculate the intrinsic carrier concentrations of these three bandgap materials at 300K: Eg = 1.12eV; and Eg = 0.66eV; where pre-factors are B=1.08x1031 K*.cm3 (1.12eV) and B = 2.31x1030 K³.cm³ (0.66€V).The U.S. Department of Energy has set the benchmark of 6% H by weight for an acceptable hydrogen storage material. Consider the following possible metals that form hydride phases: NaAlH4, LiAlH4, LaNi5H6, and TiFeH2. Which meet the DOE standard.Give reasons for the following :(a) Alumina is dissolved in cryolite for electrolysis instead of being electrolyzed directly.(b) Zinc oxide can be reduced to metal by heating with carbon but Cr2O2 cannot be reduced by heating with carbon.