M Wed 7 SepÛST24-4. Describe the differences between "real" deviationsfrom Beer's law and those due to instrumental orchemical factors.24-5. How does an electronic transition resemble a vibra-tional transition? How do they differ?24-6. Calculate the frequency in hertz of*(a) an X-ray beam with a wavelength of 2.65 Å.(b) an emission line for copper at 211.0 nm.*(c) the line at 694.3 nm produced by a ruby laser.(d) the output of a CO₂ laser at 10.6 μm.*(e) an infrared absorption peak at 19.6 µm.(f) a microwave beam at 1.86 cm.24-7. Calculate the wavelength in centimeters of*(a) an airport tower transmitting at 118.6 MHz.(b) a VOR (radio navigation aid) transmitting at114.10 kHz.24-8. A sophisticated ultraviolet/visible/near-IR instru-ment has a wavelength range of 185 to 3000 nm. Whatare its wavenumber and frequency ranges?*24-9. A typical simple infrared spectrophotometer covers awavelength range from 3 to 15 μm. Express its(a) in wavenumbers and (b) in hertz.rangein24-10. Calculate the frequency in hertz and theenergyjoules of an X-ray photon with a wavelength of 2.70 Å.*24-11. Calculate the wavelength and the energy in joulesassociated with a signal at 220 MHz.*(a)(b)*(c)*(e)(f)(h)*(c) an NMR signal at 105 MHz.(d) an infrared absorption peak with a wavenumberof 1210 cm-¹.*(i)(j)A0.1720.5200.7980.179%T44.939.683.611.15.23EL mol-¹cm-4.23 X 10³7.95 X 10³3.73 × 10³1.35 × 1049.78 × 10³(b) micrograms per liter?*(c) mass-volume percent?(d) grams per liter?24-14. Express the following absorbances in terms oftransmittance*(a) 0.0356(b) 0.895*(c) 0.379(d) 0.167*(e) 0.485(f) 0.753*(a) 27.2%(b) 0.579*(c) 30.6%(d) 3.98%*(e) 0.093(f) 63.7%24-15. Convert the accompanying transmittance data toabsorbances.-1-1cm-¹ ppm-¹0.025824-16. Calculate the percent transmittance of solutionsthat have twice the absorbance of the solutions inProblem 24-14.24-17. Calculate the absorbances of solutions with half thetransmittance of those in Problem 24-15.24-18. Evaluate the missing quantities in the accompanyingtable. Where needed, use 200 for the molar mass of theanalyte.0.0912bcm1.001:46:19오1.000.1001.001.50v1.00M1.35 x 10-41.71 X 10-³8.07 X 10-67.07 X 10-5percent7.19 X 10-5Cppm1.7633.65.24+Unless otherwise noted, all content on this page is Ⓒ Cengage LearningCopyright 2013 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s). Editorial review hasdeemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it.C

Question

M Wed 7 SepÛST24-4. Describe the differences between &#34;real&#34; deviationsfrom Beer's law and those due to instrumental orchemical factors.24-5. How does an electronic transition resemble a vibra-tional transition? How do they differ?24-6. Calculate the frequency in hertz of*(a) an X-ray beam with a wavelength of 2.65 Å.(b) an emission line for copper at 211.0 nm.*(c) the line at 694.3 nm produced by a ruby laser.(d) the output of a CO₂ laser at 10.6 μm.*(e) an infrared absorption peak at 19.6 µm.(f) a microwave beam at 1.86 cm.24-7. Calculate the wavelength in centimeters of*(a) an airport tower transmitting at 118.6 MHz.(b) a VOR (radio navigation aid) transmitting at114.10 kHz.24-8. A sophisticated ultraviolet/visible/near-IR instru-ment has a wavelength range of 185 to 3000 nm. Whatare its wavenumber and frequency ranges?*24-9. A typical simple infrared spectrophotometer covers awavelength range from 3 to 15 μm. Express its(a) in wavenumbers and (b) in hertz.rangein24-10. Calculate the frequency in hertz and theenergyjoules of an X-ray photon with a wavelength of 2.70 Å.*24-11. Calculate the wavelength and the energy in joulesassociated with a signal at 220 MHz.*(a)(b)*(c)*(e)(f)(h)*(c) an NMR signal at 105 MHz.(d) an infrared absorption peak with a wavenumberof 1210 cm-¹.*(i)(j)A0.1720.5200.7980.179%T44.939.683.611.15.23EL mol-¹cm-4.23 X 10³7.95 X 10³3.73 × 10³1.35 × 1049.78 × 10³(b) micrograms per liter?*(c) mass-volume percent?(d) grams per liter?24-14. Express the following absorbances in terms oftransmittance*(a) 0.0356(b) 0.895*(c) 0.379(d) 0.167*(e) 0.485(f) 0.753*(a) 27.2%(b) 0.579*(c) 30.6%(d) 3.98%*(e) 0.093(f) 63.7%24-15. Convert the accompanying transmittance data toabsorbances.-1-1cm-¹ ppm-¹0.025824-16. Calculate the percent transmittance of solutionsthat have twice the absorbance of the solutions inProblem 24-14.24-17. Calculate the absorbances of solutions with half thetransmittance of those in Problem 24-15.24-18. Evaluate the missing quantities in the accompanyingtable. Where needed, use 200 for the molar mass of theanalyte.0.0912bcm1.001:46:19오1.000.1001.001.50v1.00M1.35 x 10-41.71 X 10-³8.07 X 10-67.07 X 10-5percent7.19 X 10-5Cppm1.7633.65.24+Unless otherwise noted, all content on this page is Ⓒ Cengage LearningCopyright 2013 Cengage Learning. All Rights Reserved. May not be copied, scanned, or duplicated, in whole or in part. Due to electronic rights, some third party content may be suppressed from the eBook and/or eChapter(s). Editorial review hasdeemed that any suppressed content does not materially affect the overall learning experience. Cengage Learning reserves the right to remove additional content at any time if subsequent rights restrictions require it.C

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T 24-4. Describe the differences between "real" deviations from Beer's law and those due to instrumental or chemical factors. 24.14