The amount of Fe in a 0.4891-g sample of an ore was determined by a redox titration with K2Cr,0,. All the Fe was initially converted to Fe2+ followed by titration with 0.02153 M K,Cr207, which required 36.92 mL. The titration reaction is: Cr,0,2- + 6Fe?+ + 14H* - 20r+ + 6FE3+ + 7H20 How many millimoles of Fe2+ is present in the sample? a) 4.769 mmol b) 2.385 mmol c) 1.590 mmol d) 0.3974 mmol e) 0.1325 mmol If Fe in the sample exists as Fe203 (159.69 g/mol), what is the percentage by weight Fe2O3? a) 25.97% b) 38.93% c) 52.91% d) 76.45% e) 77.86% Based on the titration reaction, which of the following statements is TRUE? a) The species oxidized is Cr20,2-. b) The oxidation number of iron decreased. c) Chromium (VI) is converted to chromium (III). d) The reaction occurs under neutral conditions. e) None of the above.

Chemistry by OpenStax (2015-05-04)
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Chapter19: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 11E: Iron (II) can be oxidized to iron (III) by dichromate ion, which is reduced to chromium (III) in...
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The amount of Fe in a 0.4891-g sample of an ore was determined by a redox titration with K,Cr,07. All
the Fe was initially converted to Fe2* followed by titration with 0.02153 M K,Cr207, which required 36.92
mL. The titration reaction is:
Cr,0, + 6FE2* + 14H* → 2Cr*+ + 6Fe* + 7H2O
How many millimoles of Fe2+ is present in the sample?
a) 4.769 mmol
b) 2.385 mmol
c) 1.590 mmol
d) 0.3974 mmol
e) 0.1325 mmol
If Fe in the sample exists as Fe,O3 (159.69 g/mol), what is the percentage by weight Fe,O3?
a) 25.97%
b) 38.93%
c) 52.91%
d) 76.45%
e) 77.86%
Based on the titration reaction, which of the following statements is TRUE?
a) The species oxidized is Cr20,2-.
b) The oxidation number of iron decreased.
c) Chromium (VI) is converted to chromium (III).
d) The reaction occurs under neutral conditions.
e) None of the above.
Transcribed Image Text:The amount of Fe in a 0.4891-g sample of an ore was determined by a redox titration with K,Cr,07. All the Fe was initially converted to Fe2* followed by titration with 0.02153 M K,Cr207, which required 36.92 mL. The titration reaction is: Cr,0, + 6FE2* + 14H* → 2Cr*+ + 6Fe* + 7H2O How many millimoles of Fe2+ is present in the sample? a) 4.769 mmol b) 2.385 mmol c) 1.590 mmol d) 0.3974 mmol e) 0.1325 mmol If Fe in the sample exists as Fe,O3 (159.69 g/mol), what is the percentage by weight Fe,O3? a) 25.97% b) 38.93% c) 52.91% d) 76.45% e) 77.86% Based on the titration reaction, which of the following statements is TRUE? a) The species oxidized is Cr20,2-. b) The oxidation number of iron decreased. c) Chromium (VI) is converted to chromium (III). d) The reaction occurs under neutral conditions. e) None of the above.
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